Production of Natural Straw-Derived Sustainable Polymer Composites for a Circular Agro-Economy

Ravi Patidar, Vijay Kumar Thakur*, Ranjan Chaturvedi, Anam Khan, Tamali Mallick, Manoj Kumar Gupta and Asokan Pappu*, 
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Abstract

In this study, attempts were made for the first time to explore the unexploited wheat straw particulates (WSP) as a reinforcement filler with concentrations up to 100% in a thermoplastic polypropylene (PP) matrix to produce a new type of wood plastic composites. The WSP-PP composites were developed by melt blending using the injection molding technique and were investigated for their mechanical, structural, and thermal properties. The present study showed low-density composites with densities varying from 0.84–1.04 gm/cc. Compared to virgin polypropylene, WSP-PP composites showed enhanced impact strength, improved flexural strength and moduli, and lower water absorption. With increasing WSP concentration, the mechanical strength increases, and at 20–30% filler concentration, the composite showed a maximum tensile strength of 27.21 ± 0.67 MPa and flexural strength of 44.48 ± 0.48 MPa. The maximum impact strength of WSP-PP composites (2.04 ± 0.11 kJ/m2) was recorded at 40% filler concentration along with lower water absorption (1.67%). The addition of WSP was found to decrease the thermal conductivity of the WSP-PP composites. The findings of this study confirmed the scope of wheat straw as a potential cellulosic reinforcing filler for manufacturing a new class of green composites of high-performance characteristics which could be explored and beneficial for electrical applications, civil infrastructure, automotive parts, etc. Further, the utilization of this inexpensive raw material for the development of composites leads to a reduction in the practice of open straw burning in fields, thereby causing a decrease in CGH emissions. Thus, the realization of this innovative work will contribute to achieving the United Nations’ sustainable development goals with a sustainable approach toward building a circular economy.

Synopsis: This study explores using wheat straw particulates in a polypropylene matrix for composites for lighter and stronger materials, aligning with sustainability goals in engineering.

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生产天然秸秆可持续聚合物复合材料,促进循环农业经济
在这项研究中,我们首次尝试将未开发利用的小麦秸秆颗粒(WSP)作为一种增强填料,在热塑性聚丙烯(PP)基体中的浓度最高可达 100%,从而生产出一种新型木塑复合材料。WSP-PP 复合材料是利用注塑成型技术通过熔融混合研制而成的,并对其机械、结构和热性能进行了研究。本研究显示,低密度复合材料的密度在 0.84-1.04 gm/cc 之间。与原聚丙烯相比,WSP-PP 复合材料的冲击强度提高了,弯曲强度和模量改善了,吸水率降低了。随着 WSP 浓度的增加,机械强度也随之增加,当填料浓度为 20-30% 时,复合材料的最大拉伸强度为 27.21 ± 0.67 兆帕,弯曲强度为 44.48 ± 0.48 兆帕。填料浓度为 40% 时,WSP-PP 复合材料的冲击强度最大(2.04 ± 0.11 kJ/m2),吸水率较低(1.67%)。研究发现,添加 WSP 会降低 WSP-PP 复合材料的导热性。这项研究的结果证实,小麦秸秆作为一种潜在的纤维素增强填料,可用于制造具有高性能特征的新型绿色复合材料,并可在电气应用、民用基础设施、汽车零部件等方面发挥有益作用。此外,利用这种价格低廉的原材料开发复合材料,可以减少田间露天焚烧秸秆的做法,从而减少 CGH 排放量。因此,这项创新工作的实现将有助于以可持续的方式建设循环经济,从而实现联合国的可持续发展目标。 简介:本研究探讨了在聚丙烯基体中使用小麦秸秆颗粒制造复合材料,以获得更轻、更强的材料,从而实现工程领域的可持续发展目标。
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