Photogalvanic effect in the armchair and zigzag photodetectors based on the graphene-like BC3 monolayer

IF 2.4 3区 化学 Q4 CHEMISTRY, PHYSICAL Chemical Physics Pub Date : 2024-08-11 DOI:10.1016/j.chemphys.2024.112416
Xi Fu , Jian Lin , Guangyao Liang , Wenhu Liao , Haixia Gao , Liming Li
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Abstract

The graphene-like BC3 monolayer has been experimentally prepared. In this paper, based on this BC3 monolayer, we built its armchair and zigzag photodetectors and studied linear and elliptical photogalvanic effects (PGEs) in these devices. It was found that produced photocurrents in the armchair and zigzag BC3 photodetectors mainly show cosine and sine relations on double times of linear or elliptical polarized angle, respectively. Moreover, since the decreasing of symmetry from D6H to C2v or Cs at the vacancy- and substitution-doping situations, the photocurrents in the armchair and zigzag BC3 photodetectors increased about 10–100 times, and the photocurrents even may be detected in experiments. Furthermore, the armchair and zigzag BC3 photodetectors are all polarization-sensitive for their high extinction ratios. In view of that the BC3 monolayer has been prepared, our work manifested great potential applications of the PGE-driven BC3 photodetectors in high performance and low energy-consumption optoelectronic and nanoelectronic devices.

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基于类石墨烯 BC3 单层的扶手椅型和之字形光电探测器中的光电效应
实验制备了类石墨烯 BC3 单层。在本文中,我们以这种 BC3 单层为基础,构建了其扶手和人字形光电探测器,并研究了这些器件中的线性和椭圆形光电效应(PGEs)。研究发现,在扶手和人字形 BC3 光电探测器中产生的光电流主要分别与线性或椭圆偏振角的两倍呈余弦和正弦关系。此外,在空位掺杂和置换掺杂的情况下,由于对称性从 D6H 下降到 C2v 或 Cs,臂形和人字形 BC3 光电探测器中的光电流增加了约 10-100 倍,甚至可以在实验中检测到光电流。此外,臂形和人字形 BC3 光电探测器都具有高消光比的偏振敏感性。鉴于 BC3 单层已经制备完成,我们的工作表明 PGE 驱动的 BC3 光电探测器在高性能、低能耗的光电和纳米电子器件中具有巨大的应用潜力。
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来源期刊
Chemical Physics
Chemical Physics 化学-物理:原子、分子和化学物理
CiteScore
4.60
自引率
4.30%
发文量
278
审稿时长
39 days
期刊介绍: Chemical Physics publishes experimental and theoretical papers on all aspects of chemical physics. In this journal, experiments are related to theory, and in turn theoretical papers are related to present or future experiments. Subjects covered include: spectroscopy and molecular structure, interacting systems, relaxation phenomena, biological systems, materials, fundamental problems in molecular reactivity, molecular quantum theory and statistical mechanics. Computational chemistry studies of routine character are not appropriate for this journal.
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