Selective C-Methylenation of N-Unsubstituted Indoles Using CO₂ Under NaBH₄/I₂ System.

IF 7.5 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY ChemSusChem Pub Date : 2025-01-14 Epub Date: 2024-10-25 DOI:10.1002/cssc.202401491

Zhiqiang Guo, Jinglong Wu, Xuehong Wei, Chanjuan Xi

引用次数: 0

Abstract

The selective C-methylenation of N-unsubstituted indoles using CO₂ as the C1 source to access diindolylmethane (DIM) and its derivatives is described. This reaction provides a novel method for four-electron reductive functionalization of CO₂ with N-unsubstituted indoles via formation of C-CH₂-C bonds, and a new access to molecular structures.

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

在 NaBH4/I2 系统下使用 CO2 对 N-未取代吲哚进行选择性 C-甲基化。

本研究描述了以 CO2 为 C1 源对 N-未取代吲哚进行选择性 C-亚甲基化以获得二吲哚甲烷（DIM）及其衍生物的过程。该反应为 CO2 与 N-未取代吲哚通过形成 C-CH2-C 键进行四电子还原官能化提供了一种新方法，也为分子结构提供了一种新途径。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文去求助

来源期刊

ChemSusChem 化学-化学综合

CiteScore

15.80

自引率

4.80%

发文量

555

审稿时长

1.8 months

期刊介绍： ChemSusChem Impact Factor (2016): 7.226 Scope: Interdisciplinary journal Focuses on research at the interface of chemistry and sustainability Features the best research on sustainability and energy Areas Covered: Chemistry Materials Science Chemical Engineering Biotechnology

Selective C-Methylenation of N-Unsubstituted Indoles Using CO2 Under NaBH4/I2 System.

Abstract

Selective C-Methylenation of N-Unsubstituted Indoles Using CO₂ Under NaBH₄/I₂ System.