Microstructural evolution, enhanced mechanical properties, and complex shapes design in high solid content alumina ceramics through additive manufacturing

Abstract

Manufacturing industrially profitable high solid-loading ceramic materials with finely designed complex shapes is an exciting yet challenging in sustainable additive manufacturing. Here, we propose a resin strategy to achieve a high solid-loading content of 62 vol% alumina slurry for 3D printing high-quality complex shapes using digital light processing (DLP) technology. Remarkably, both high solid-loading content and tuned sintering temperature emerge as key factors in ensuring optimal print quality and mechanical performance. With this strategy, the ceramic slurry containing 62 vol% exhibits lower shear rate and improved layer adhesion. The burnout treatment was designed based on the DSC-TGA results, followed by sintering in an air atmosphere. Comprehensive physical measurements were achieved, alongside precise structural characterization at multilength scales in situ. In depth exploration of post-sintering analysis revealed no changes in phase composition or chemical bonding. The optimum overall performance of sintered specimen exhibited shrinkage of 8.3 %, 8.8 %, and 11.5 % in the X, Y, and Z directions, with a bulk density of 3.76 g/cm³. Mechanical testing demonstrated superior flexural strength of 247.23 MPa, nanoindentation hardness of 30.9 GPa, and modulus of 428.35 GPa. This high-precision printing strategy may significantly contribute to understanding the structure-property relationship of DLP-3D printed Al₂O₃ ceramic and opening avenue for the applications of high-strength parts in demanding environments.