Nonvolatile Electro-optic Response of Graphene Driven by Ferroelectric Polarization.

IF 11.3 1区 化学 Q1 CHEMISTRY, PHYSICAL ACS Catalysis Pub Date : 2024-09-18 Epub Date: 2024-09-03 DOI:10.1021/acs.nanolett.4c02625
Jianghong Wu, Jialing Jian, Hui Ma, Yuting Ye, Bo Tang, Zhuang Qian, Qingyan Deng, Boshu Sun, Shi Liu, Hongtao Lin, Lan Li
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Abstract

Two-dimensional materials (2DMs) have exhibited remarkably tunable optical characteristics, which have been applied for significant applications in communications, sensing, and computing. However, the reported tunable optical properties of 2DMs are almost volatile, impeding them in the applications of multifarious emerging frameworks such as programmable operation and neuromorphic computing. In this work, nonvolatile electro-optic response is developed by the graphene-Al2O3-In2Se3 heterostructure integrating with microring resonators (MRRs). In such compact devices, the optical absorption coefficient of graphene is substantially tuned by the out-of-plane ferroelectric polarization in α-In2Se3, resulting in a nonvolatile optical transmission in MRRs. This work demonstrates that integrating graphene with ferroelectric materials paves the way to develop nonvolatile devices in photonic circuits for emerging applications such as optical neural networks.

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铁电极化驱动石墨烯的非易失性电光响应。
二维材料(2DM)具有显著的可调谐光学特性,已在通信、传感和计算领域得到广泛应用。然而,所报道的二维材料的可调光学特性几乎是不稳定的,这阻碍了它们在可编程操作和神经形态计算等多种新兴框架中的应用。在这项工作中,石墨烯-Al2O3-In2Se3 异质结构与微oring 谐振器 (MRR) 相结合,开发出了非易失性电光响应。在这种紧凑型器件中,石墨烯的光吸收系数可通过 α-In2Se3 中的面外铁电极化进行大幅调整,从而在 MRR 中实现非易失性光传输。这项工作表明,将石墨烯与铁电材料集成在一起,为开发光子电路中的非易失性器件铺平了道路,可用于光学神经网络等新兴应用。
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来源期刊
ACS Catalysis
ACS Catalysis CHEMISTRY, PHYSICAL-
CiteScore
20.80
自引率
6.20%
发文量
1253
审稿时长
1.5 months
期刊介绍: ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels. The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.
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