Fluorescence hyperspectral imaging technology combined with chemometrics for kiwifruit quality attribute assessment and non-destructive judgment of maturity.

IF 5.6 1区 化学 Q1 CHEMISTRY, ANALYTICAL Talanta Pub Date : 2024-12-01 Epub Date: 2024-08-30 DOI:10.1016/j.talanta.2024.126793
Zhiyong Zou, Qianlong Wang, Qingsong Wu, Menghua Li, Jiangbo Zhen, Dongyu Yuan, Yuchen Xiao, Chong Xu, Shutao Yin, Man Zhou, Lijia Xu
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Abstract

Dry matter content (DMC), firmness and soluble solid content (SSC) are important indicators for assessing the quality attributes and determining the maturity of kiwifruit. However, traditional measurement methods are time-consuming, labor-intensive, and destructive to the kiwifruit, leading to resource wastage. In order to solve this problem, this study has tracked the flowering, fruiting, maturing and collecting processes of Ya'an red-heart kiwifruit, and has proposed a non-destructive method for kiwifruit quality attribute assessment and maturity identification that combines fluorescence hyperspectral imaging (FHSI) technology and chemometrics. Specifically, first of all, three different spectral data preprocessing methods were adopted, and PLSR was used to evaluate the quality attributes (DMC, firmness, and SSC) of kiwifruit. Next, the differences in accuracy of different models in discriminating kiwifruit maturity were compared, and an ensemble learning model based on LightGBM and GBDT models was constructed. The results indicate that the ensemble learning model outperforms single machine learning models. In addition, the application effects of the 'Convolutional Neural Network'-'Multilayer Perceptron' (CNN-MLP) model under different optimization algorithms were compared. To improve the robustness of the model, an improved whale optimization algorithm (IWOA) was introduced by modifying the acceleration factor. Overall, the IWOA-CNN-MLP model performs the best in discriminating the maturity of kiwifruit, with Accuracytest of 0.916 and Loss of 0.23. In addition, compared with the basic model, the accuracy of the integrated learning model SG-MSC-SEL was improved by about 12%-20 %. The research findings will provide new perspectives for the evaluation of kiwifruit quality and maturity discrimination using FHSI and chemometric methods, thereby promoting further research and applications in this field.

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荧光高光谱成像技术与化学计量学相结合,用于猕猴桃质量属性评估和成熟度的非破坏性判断。
干物质含量(DMC)、硬度和可溶性固体含量(SSC)是评估猕猴桃质量属性和确定其成熟度的重要指标。然而,传统的测量方法耗时、耗力,而且对猕猴桃造成破坏,导致资源浪费。为了解决这一问题,本研究跟踪了雅安红心猕猴桃的开花、结果、成熟和采收过程,提出了一种结合荧光高光谱成像(FHSI)技术和化学计量学的非破坏性猕猴桃品质属性评估和成熟度鉴定方法。具体而言,首先采用三种不同的光谱数据预处理方法,并利用 PLSR 评估猕猴桃的质量属性(DMC、硬度和 SSC)。然后,比较了不同模型在判别猕猴桃成熟度方面的准确性差异,并构建了基于 LightGBM 和 GBDT 模型的集合学习模型。结果表明,集合学习模型优于单一机器学习模型。此外,还比较了 "卷积神经网络"-"多层感知器"(CNN-MLP)模型在不同优化算法下的应用效果。为了提高模型的鲁棒性,通过修改加速因子引入了改进的鲸鱼优化算法(IWOA)。总体而言,IWOA-CNN-MLP 模型在判别猕猴桃成熟度方面表现最佳,准确度为 0.916,损失为 0.23。此外,与基本模型相比,综合学习模型 SG-MSC-SEL 的准确度提高了约 12%-20%。这些研究成果将为利用 FHSI 和化学计量学方法评价猕猴桃质量和成熟度鉴别提供新的视角,从而促进该领域的进一步研究和应用。
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来源期刊
Talanta
Talanta 化学-分析化学
CiteScore
12.30
自引率
4.90%
发文量
861
审稿时长
29 days
期刊介绍: Talanta provides a forum for the publication of original research papers, short communications, and critical reviews in all branches of pure and applied analytical chemistry. Papers are evaluated based on established guidelines, including the fundamental nature of the study, scientific novelty, substantial improvement or advantage over existing technology or methods, and demonstrated analytical applicability. Original research papers on fundamental studies, and on novel sensor and instrumentation developments, are encouraged. Novel or improved applications in areas such as clinical and biological chemistry, environmental analysis, geochemistry, materials science and engineering, and analytical platforms for omics development are welcome. Analytical performance of methods should be determined, including interference and matrix effects, and methods should be validated by comparison with a standard method, or analysis of a certified reference material. Simple spiking recoveries may not be sufficient. The developed method should especially comprise information on selectivity, sensitivity, detection limits, accuracy, and reliability. However, applying official validation or robustness studies to a routine method or technique does not necessarily constitute novelty. Proper statistical treatment of the data should be provided. Relevant literature should be cited, including related publications by the authors, and authors should discuss how their proposed methodology compares with previously reported methods.
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