Influence of loading method on the performance of Zn/SAPO-34 catalysts and its catalytic preparation of 5-Hydroxymethylfurfural from fructose dehydration

Abstract

A diverse suite of Zn-SAPO-34 catalysts was synthesized employing three distinct methodologies for the incorporation of zinc species: thermal ion exchange, wet impregnation, and physical mixing. The catalysts were characterized using various analytical techniques including XRD, FT-IR, BET, SEM, XRF, XPS, NH₃-TPD, and Py-IR, to elucidate the crystal structure, morphology, surface acidity, and the presence of zinc species within the catalysts. The study showed that the method of zinc introduction markedly impacts the physicochemical properties of the catalysts. Different approaches to introducing zinc species significantly influence the acid strength and type on the catalyst surface, with variations in the existing states of zinc across the catalysts. Specifically, zinc species introduced via thermal ion exchange coexist as ZnOH⁺ and ZnO within the catalyst, whereas those from wet impregnation and physical mixing are individually present as either ZnOH⁺ or ZnO. Furthermore, the study examined the catalytic performance of these Zn-SAPO-34 catalysts in the dehydration of fructose to produce 5-hydroxymethylfurfural (HMF). Catalysts prepared via thermal ion exchange exhinited superior performance, achieving an remarkable HMF yield of 94.6 %. Additionally, in situ infrared technology was used to investigate the effect of zinc species introduction on the fructose dehydration process, indicating suggesting that the introduction of zinc species enhances the transformation of fructose molecules.