Ellina Bernard , Daniel Rentsch , Raphael Kuhn , Guillaume Habert , Pietro Lura
{"title":"Earth stabilisation with MgO-based cement","authors":"Ellina Bernard , Daniel Rentsch , Raphael Kuhn , Guillaume Habert , Pietro Lura","doi":"10.1016/j.cemconres.2024.107655","DOIUrl":null,"url":null,"abstract":"<div><p>This study compares, for the first time, MgO-based (MB) cement and Portland-based (PB) cement for stabilizing earth mortars. While MB and PB earth mortars reach similar strength, MB cement stabilization demonstrates superior early-age performance. Thermogravimetric analysis, X-ray diffraction, <sup>29</sup>Si and <sup>31</sup>P NMR spectroscopies show that the cement reacts in both systems and allow to establish the phase assemblages. The stabilized earth pastes contain less hydroxide phases, indicating a pozzolanic reaction in both cases.</p><p>MB-stabilized clay mortars retain about 1/3 of the compressive strength of pure MB mortar, while with PB this proportion is only 1/5. This difference demonstrates that MB is more compatible with clay minerals and more suitable for stabilizing earth mortars. If MB cement could be produced with renewable energy from CO<sub>2</sub>-free sources (instead of from magnesite), stabilization of earth mortars with MB would be substantially more CO<sub>2</sub> efficient than with PB.</p></div>","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"186 ","pages":"Article 107655"},"PeriodicalIF":10.9000,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0008884624002369/pdfft?md5=87c741b9ec94508b5517aef274ebc911&pid=1-s2.0-S0008884624002369-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cement and Concrete Research","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0008884624002369","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CONSTRUCTION & BUILDING TECHNOLOGY","Score":null,"Total":0}
引用次数: 0
Abstract
This study compares, for the first time, MgO-based (MB) cement and Portland-based (PB) cement for stabilizing earth mortars. While MB and PB earth mortars reach similar strength, MB cement stabilization demonstrates superior early-age performance. Thermogravimetric analysis, X-ray diffraction, 29Si and 31P NMR spectroscopies show that the cement reacts in both systems and allow to establish the phase assemblages. The stabilized earth pastes contain less hydroxide phases, indicating a pozzolanic reaction in both cases.
MB-stabilized clay mortars retain about 1/3 of the compressive strength of pure MB mortar, while with PB this proportion is only 1/5. This difference demonstrates that MB is more compatible with clay minerals and more suitable for stabilizing earth mortars. If MB cement could be produced with renewable energy from CO2-free sources (instead of from magnesite), stabilization of earth mortars with MB would be substantially more CO2 efficient than with PB.
期刊介绍:
Cement and Concrete Research is dedicated to publishing top-notch research on the materials science and engineering of cement, cement composites, mortars, concrete, and related materials incorporating cement or other mineral binders. The journal prioritizes reporting significant findings in research on the properties and performance of cementitious materials. It also covers novel experimental techniques, the latest analytical and modeling methods, examination and diagnosis of actual cement and concrete structures, and the exploration of potential improvements in materials.