Electromagnetic interference shielding properties of PMMA modified-Co0.5Zn0.5Fe2O4 − polyaniline composites

Parthasarathi Bera, R. V. Lakshmi, R. P. S. Chakradhar, Suryasarathi Bose, Harish C. Barshilia
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Abstract

Present work reports solution combustion synthesis (SCS) of Co0.5Zn0.5Fe2O4 spinel ferrite, its chemical modification with polymethylmethacrylate (PMMA), synthesis of polyaniline (PANI), and electromagnetic interference (EMI) shielding properties of their composites. Both as-prepared and PMMA-modified Co0.5Zn0.5Fe2O4 adopt cubic spinel structure as shown by X-ray diffraction studies. Field emission scanning electron microscopy images show the agglomerated and microporous nature of the ferrites. High resolution transmission electron microscopy image of as-prepared Co0.5Zn0.5Fe2O4 shows lattice fringes related to (311) plane of the spinel structure. X-ray photoelectron spectroscopy studies reveal the presence of Co2+, Zn2+, and Fe3+ in tetrahedral and octahedral coordinations in the ferrite. EMI shielding properties are evaluated for PMMA-modified Co0.5Zn0.5Fe2O4 and PANI composites in different weight ratios. Composites containing PMMA-modified ferrite and PANI with 50:50 and 10:90 weight ratios show the best performance among all the composites in 2−20 GHz frequency range. Optimized PMMA-modified Co0.5Zn0.5Fe2O4 and PANI composite with the ratio of 10:90 shows shielding effectiveness (SE) values of −16.6 to −24.2 dB in 2−20 GHz frequency region.

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PMMA 改性-Co0.5Zn0.5Fe2O4-聚苯胺复合材料的电磁干扰屏蔽性能
本研究报告介绍了溶液燃烧合成(SCS)Co0.5Zn0.5Fe2O4 尖晶石铁氧体、用聚甲基丙烯酸甲酯(PMMA)对其进行化学改性、合成聚苯胺(PANI)及其复合材料的电磁干扰(EMI)屏蔽性能。X 射线衍射研究表明,原制备的和经 PMMA 改性的 Co0.5Zn0.5Fe2O4 都具有立方尖晶石结构。场发射扫描电子显微镜图像显示了铁氧体的团聚和微孔性质。制备的 Co0.5Zn0.5Fe2O4 的高分辨率透射电子显微镜图像显示了与尖晶石结构的(311)面有关的晶格条纹。X 射线光电子能谱研究显示,铁氧体中存在四面体和八面体配位的 Co2+、Zn2+ 和 Fe3+。对不同重量比的 PMMA 改性 Co0.5Zn0.5Fe2O4 和 PANI 复合材料的 EMI 屏蔽性能进行了评估。在 2-20 GHz 频率范围内,含有 PMMA 改性铁氧体和 PANI(重量比分别为 50:50 和 10:90)的复合材料在所有复合材料中表现出最佳性能。优化的 PMMA 改性 Co0.5Zn0.5Fe2O4 和 PANI 复合材料的重量比为 10:90,在 2-20 GHz 频率范围内显示出 -16.6 至 -24.2 dB 的屏蔽效能(SE)值。
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