Near-infrared surface sensitizing of PA12 to enable diode laser-based Powder Bed Fusion

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Abstract

Laser-based powder bed (PBF-LB) fusion of polymers has emerged as a versatile technique for additive manufacturing (AM), offering laynew processing freedom through promising beam-shaping techniques. This study explores a novel approach to overcome the NIR absorption limitations of the market-dominant standard material polyamide 12 (PA12) by increasing the sensitivity for effective diode laser processing through surface modification with NIR-absorbing nanoparticles (NPs). The investigation encompasses nano sensitization strategies and theoretical analysis of energy input to the polymer, alongside comparisons with volume-modified polymer feedstocks, demonstrating that diode laser printing of surface-modified (s-mod) PA12 is possible with a macroscopic quality comparable to a commercially available volume-modified (v-mod) feedstock.

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对 PA12 进行近红外表面敏化,实现基于二极管激光的粉末床融合
基于激光的粉末床(PBF-LB)聚合物熔融技术已成为增材制造(AM)的一种多功能技术,通过前景广阔的光束整形技术提供了全新的加工自由度。本研究探索了一种新方法,通过使用吸收近红外的纳米颗粒(NPs)进行表面改性,提高二极管激光加工的灵敏度,从而克服市场主流标准材料聚酰胺 12(PA12)的近红外吸收限制。这项研究包括纳米敏化策略和聚合物能量输入理论分析,以及与体积改性聚合物原料的比较,结果表明二极管激光打印表面改性(s-mod)聚酰胺 12 是可行的,其宏观质量可与市场上的体积改性(v-mod)原料相媲美。
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