Performance of novel engineered materials from nano‐silica incorporated phenol‐formaldehyde‐flax fabric hybrid composite: Thermal, wear, aging and biodegradability analysis

IF 3.9 3区 化学 Q2 POLYMER SCIENCE Journal of Polymer Science Pub Date : 2024-08-14 DOI:10.1002/pol.20240317
Ravindran Lakshmipriya, T. G. Unnikrishnan, C. George Soney, M. S. Sreekala, Thomas Sabu
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Abstract

With the growing awareness of environmental issues, natural fiber composites have emerged as a viable substitute for conventional polymer composites. The usage of natural fiber reinforced with nano fillers composites has increased significantly in recent years, especially in the building, automotive, and aerospace industries. This research explores the effect of nano‐silica in tribological, thermal behavior, water diffusion properties and biodegradation of flax fabric/phenol‐formaldehyde hybrid composites. We have fabricated the hybrid composites utilizing compression molding technique. The results showed that after reaching the lowest value for 4 nanosilica (NS), the volumetric wear rose when the addition of nano‐silica was increased. However, the volumetric wear decreased as the weight percentage of nano‐silica improved. At lower sliding speeds (1 m/s), the VW value is between 0.06782 and 0.05455 cm3, but at higher sliding speeds (3 m/s), it is roughly 0.09253–0.06187 cm3. The thermal stability was improved for 1 NS, 2 NS, and 3 NS is 1.20%, 1.64%, and 0.71%, respectively. At three different temperatures (30, 60, and 90°C) the impact of nano‐silica on the water diffusion behavior of PF‐flax fabric hybrid composites was examined. 2 NS showed the least amount of water sorption. it was noted that the three coefficients—Diffusion, Sorption, and Permeation‐were all declining when compared to PF‐flax fabric composites devoid of nano‐silica following computing the Arrhenius values, the free energy change was always negative, indicating the spontaneity of sorption in non‐reinforced samples. The tensile strength of every composite in this investigation was marginally changed by the water aging process.

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纳米二氧化硅与苯酚-甲醛-亚麻织物混合复合材料的新型工程材料性能:热、磨损、老化和生物降解性分析
随着人们对环境问题的认识不断提高,天然纤维复合材料已成为传统聚合物复合材料的可行替代品。近年来,使用纳米填料增强的天然纤维复合材料的用量大幅增加,尤其是在建筑、汽车和航空航天工业中。本研究探讨了纳米二氧化硅对亚麻织物/苯酚-甲醛混合复合材料的摩擦学、热行为、水扩散特性和生物降解的影响。我们利用压缩成型技术制造了这种混合复合材料。结果表明,在 4 纳米二氧化硅(NS)达到最低值后,随着纳米二氧化硅添加量的增加,体积磨损上升。然而,随着纳米二氧化硅重量百分比的增加,体积磨损也随之减少。在较低的滑动速度(1 m/s)下,VW 值介于 0.06782 和 0.05455 cm3 之间,但在较高的滑动速度(3 m/s)下,VW 值大致为 0.09253-0.06187 cm3。1 NS、2 NS 和 3 NS 的热稳定性分别提高了 1.20%、1.64% 和 0.71%。在三种不同温度(30、60 和 90°C)下,研究了纳米二氧化硅对 PF-亚麻织物混合复合材料水扩散行为的影响。计算阿伦尼乌斯值后发现,与不含纳米二氧化硅的 PF-亚麻织物复合材料相比,三个系数--扩散系数、吸附系数和渗透系数--均有所下降,自由能变化始终为负,这表明非增强样品具有自发性吸附。本研究中每种复合材料的拉伸强度在水老化过程中都略有变化。
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来源期刊
Journal of Polymer Science
Journal of Polymer Science POLYMER SCIENCE-
CiteScore
6.30
自引率
5.90%
发文量
264
期刊介绍: Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology. As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology.
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