First Finding of Vivianite in Kara Sea Bottom Sediments

IF 1.3 4区 地球科学 Q4 OCEANOGRAPHY Oceanology Pub Date : 2024-08-26 DOI:10.1134/s0001437024700243
N. V. Kozina, L. Ye. Reykhard, M. D. Kravchishina, A. S. Filippov, O. M. Dara, Ye. A. Novichkova, L. A. Lozinskaya, S. V. Slomnyuk
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Abstract

Vivianite, an authigenic mineral from the phosphate class, was discovered in Kara Sea bottom sediments for the first time. Similar finds of vivianite were previously known only for the outer shelf of the Laptev Sea, the northern Barents Sea, and the eastern White Sea. Its presence in the subsurface sedimentary strata indicates desalinization of the surface layer of the sea. Core 7444, sampled in a tectonic depression in the Kara Sea during the first stage of cruise 89 of the R/V Akademik Mstislav Keldysh (2022), uncovered Holocene sedimentary strata up to 6.19 m thick. Coarse-silty and sandy vivianite formations are found throughout the entire core, starting from 0.11 m. Vivianite was investigated by a set of methods: optical microscopy, X-ray diffraction, and scanning electron microscopy with energy dispersive spectroscopy. The morphology, microstructures, and chemical composition of vivianite formations have been studied. Three morphological types of these formations have been identified: micronodules and their intergrowths, crystalline aggregates and their intergrowths, and tubular aggregates.

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卡拉海底沉积物中首次发现薇薇安石
摘要 在喀拉海海底沉积物中首次发现了一种自生磷酸盐类矿物--维维安石。以前只在拉普捷夫海外陆架、巴伦支海北部和白海东部发现过类似的维维安岩。它出现在表层下沉积地层表明海水表层已经脱盐。Akademik Mstislav Keldysh 号考察船(2022 年)在第 89 号考察航行的第一阶段,在喀拉海的一个构造洼地对岩心 7444 进行了取样,发现了厚达 6.19 米的全新世沉积地层。通过光学显微镜、X 射线衍射和扫描电子显微镜与能量色散光谱等一系列方法对薇安石进行了研究。对薇安石地层的形态、微观结构和化学成分进行了研究。确定了这些岩层的三种形态类型:微晶块及其相互生长、结晶聚集体及其相互生长和管状聚集体。
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来源期刊
Oceanology
Oceanology 地学-海洋学
CiteScore
2.00
自引率
20.00%
发文量
83
审稿时长
6-12 weeks
期刊介绍: Oceanology, founded in 1961, is the leading journal in all areas of the marine sciences. It publishes original papers in all fields of theoretical and experimental research in physical, chemical, biological, geological, and technical oceanology. The journal also offers reviews and information about conferences, symposia, cruises, and other events of interest to the oceanographic community.
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