Studying the Effect of Chemical Activated Kaolinite on Organic Matter Adsorption from Crude Phosphoric Acid (H3PO4)

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED Russian Journal of Applied Chemistry Pub Date : 2024-08-20 DOI:10.1134/S1070427224020095
W. M. Youssef, A. A. Elzoghby, E. M. Helmy, Khalil A. Khalil, H. S. Gado, A. A. Rateb
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Abstract

Purification of phosphoric acid (H3PO4) is considered major problem and several ways have been evaluated. In this study, two different types of clay, raw kaolinite clay (RKC) and chemical kaolinite clay (CKC) were used for the removal of organic matter (OM). The used samples were characterized by X-ray diffraction, SEM, FT-IR, and chemical analysis. The adsorptive capacities of the samples were investigated by using them to adsorb organic matter from crude-strength phosphoric acid. Removal of organic matter from crude phosphoric acid was carried out by adsorption using RKC and СKC minerals. The different factors affecting the adsorption process were investigated. The experimental data exhibited that the clay treated with sulfuric acid had the highest organic matter adsorption capacity. The equilibrium adsorption data were analyzed using the Langmuir and Freundlich isotherms. The results showed that the equilibrium adsorption capacities for the two adsorbents followed the Langmuir model.

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研究化学活化高岭石对粗磷酸(H3PO4)有机物吸附的影响
摘要磷酸(H3PO4)的净化被认为是一个主要问题,已经对几种方法进行了评估。在这项研究中,使用了两种不同类型的粘土:生高岭石粘土(RKC)和化学高岭石粘土(CKC)来去除有机物(OM)。所用样品通过 X 射线衍射、扫描电子显微镜、傅立叶变换红外光谱和化学分析进行了表征。通过使用这些样品吸附粗浓磷酸中的有机物,研究了它们的吸附能力。利用 RKC 和 СKC 矿物的吸附作用去除粗磷酸中的有机物。研究了影响吸附过程的不同因素。实验数据表明,用硫酸处理过的粘土具有最高的有机物吸附能力。利用 Langmuir 和 Freundlich 等温线分析了平衡吸附数据。结果表明,两种吸附剂的平衡吸附容量均遵循 Langmuir 模型。
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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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