{"title":"A question of time and space: A model approach to the synchronicity of gypsum and halite during the Messinian Salinity Crisis","authors":"Ronja Monika Ebner, Paul Meijer","doi":"10.5194/cp-2024-58","DOIUrl":null,"url":null,"abstract":"<strong>Abstract.</strong> Saltgiants, although well studies, still offer some unsolved questions. One example is the Messinian Saltgiant which formed during the Messinian Salinity Crisis (MSC, 5.97 to 5.33 Ma) in the Mediterranean Sea. While a common assumption is that gypsum precipitated in the marginal parts of the basin before halite formed in the deeper part of the basin, this could be not yet been confirmed. Indeed, it has also been suggested that, while the primary lower gypsum was forming, the deep basins was already accumulating halite. In this study we use box modeling to investigate the distribution of halite and gypsum deposits for different configurations. Due to a dimensionless description of basin restriction, our results can be transferred to other basins. With this approach we find that under the right conditions all configurations lead to a simultaneous but spatially separated precipitation of gypsum and halite. They would, however, not lead to the spatial pattern that is observed in the Mediterranean, i.e. halite deposition in the deep basins while gypsum is deposited in the margins. Based on those results we propose a timeline for a salinifying basin. For an average salinity above gypsum but below halite saturation, halite is first formed in a sufficiently restricted margin, and only once the average salinity approaches the one of halite saturation can it also form in open areas of the basin due to horizontal salinity gradients. Once the whole basin has reached halite saturation, gypsum only forms in margins with a positive local freshwater budget. Such a mechanism would produce less than 1 m of gypsum within 25 kyr. We thus conclude that a simultaneous, yet spatially separated precipitation of gypsum and halite within a one basin is possible, but unlikely to have led to the massive primary lower gypsum outcrops in the Mediterranean, while halite formed in the deeper parts of the same sub-basin.","PeriodicalId":10332,"journal":{"name":"Climate of The Past","volume":"24 1","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Climate of The Past","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.5194/cp-2024-58","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Abstract. Saltgiants, although well studies, still offer some unsolved questions. One example is the Messinian Saltgiant which formed during the Messinian Salinity Crisis (MSC, 5.97 to 5.33 Ma) in the Mediterranean Sea. While a common assumption is that gypsum precipitated in the marginal parts of the basin before halite formed in the deeper part of the basin, this could be not yet been confirmed. Indeed, it has also been suggested that, while the primary lower gypsum was forming, the deep basins was already accumulating halite. In this study we use box modeling to investigate the distribution of halite and gypsum deposits for different configurations. Due to a dimensionless description of basin restriction, our results can be transferred to other basins. With this approach we find that under the right conditions all configurations lead to a simultaneous but spatially separated precipitation of gypsum and halite. They would, however, not lead to the spatial pattern that is observed in the Mediterranean, i.e. halite deposition in the deep basins while gypsum is deposited in the margins. Based on those results we propose a timeline for a salinifying basin. For an average salinity above gypsum but below halite saturation, halite is first formed in a sufficiently restricted margin, and only once the average salinity approaches the one of halite saturation can it also form in open areas of the basin due to horizontal salinity gradients. Once the whole basin has reached halite saturation, gypsum only forms in margins with a positive local freshwater budget. Such a mechanism would produce less than 1 m of gypsum within 25 kyr. We thus conclude that a simultaneous, yet spatially separated precipitation of gypsum and halite within a one basin is possible, but unlikely to have led to the massive primary lower gypsum outcrops in the Mediterranean, while halite formed in the deeper parts of the same sub-basin.
期刊介绍:
Climate of the Past (CP) is a not-for-profit international scientific journal dedicated to the publication and discussion of research articles, short communications, and review papers on the climate history of the Earth. CP covers all temporal scales of climate change and variability, from geological time through to multidecadal studies of the last century. Studies focusing mainly on present and future climate are not within scope.
The main subject areas are the following:
reconstructions of past climate based on instrumental and historical data as well as proxy data from marine and terrestrial (including ice) archives;
development and validation of new proxies, improvements of the precision and accuracy of proxy data;
theoretical and empirical studies of processes in and feedback mechanisms between all climate system components in relation to past climate change on all space scales and timescales;
simulation of past climate and model-based interpretation of palaeoclimate data for a better understanding of present and future climate variability and climate change.