Efficient removal of rhodamine B dye using myrrh-based magnetized multi-walled carbon nanotubes as adsorbent

IF 3 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Adsorption Pub Date : 2024-09-06 DOI:10.1007/s10450-024-00533-z
Mushtaq Hussain, Syed Sulaiman Hussaini, Mohammad Shariq, Hanan A. Althikrallah, Noha Al-Qasmi, Kondaiah Seku, Shabbir Ahmed Kazi
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Abstract

A novel strategy was used to successfully remove rhodamine B dye from contaminated water by combining magnetized multi-walled carbon nanotubes (MWCNTs) with myrrh gum as an adsorbent. The shape and structure of the prepared adsorbent were charecterized using X-ray powder diffraction analysis, FTIR, SEM, and TEM. A batch approach was used to study the effect of the adsorbent on rhodamine B removal, and several variables were considered, including pH, agitation time, and adsorbent dosage. The findings revealed that rhodamine B dye removal was best at a basic pH of 8, with a 0.05 g adsorbent dosage, within 30 min. Different models were utilized to analyze the isotherm data obtained during the investigations. The adsorbent exhibited the highest adsorption capacity for rhodamine B removal, reaching 332.22 mg/g. The regression analysis indicated appropriate adsorption kinetics with a pseudo-second order kinetics and an R2 value of 0.999. The thermodynamic analysis specified that the removal process exhibits endothermic characteristics, spontaneous behavior, and involves chemisorption. The obtained results demonstrate the efficacy of the adsorbent in the context of water treatment.

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用没药基磁化多壁碳纳米管作为吸附剂高效去除罗丹明 B 染料
通过将磁化多壁碳纳米管(MWCNTs)与没药胶结合作为吸附剂,一种新颖的策略成功地去除了污染水中的罗丹明 B 染料。利用 X 射线粉末衍射分析、傅立叶变换红外光谱、扫描电镜和 TEM 分析了所制备吸附剂的形状和结构。采用批次法研究了吸附剂对罗丹明 B 的去除效果,并考虑了多个变量,包括 pH 值、搅拌时间和吸附剂用量。研究结果表明,在碱性 pH 值为 8、吸附剂用量为 0.05 克的条件下,罗丹明 B 染料的去除率在 30 分钟内达到最佳。利用不同的模型分析了研究过程中获得的等温线数据。该吸附剂对罗丹明 B 的吸附去除率最高,达到 332.22 毫克/克。回归分析表明,该吸附剂的吸附动力学为假二阶动力学,R2 值为 0.999。热力学分析表明,去除过程表现出内热特性、自发行为和化学吸附。所得结果证明了该吸附剂在水处理方面的功效。
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来源期刊
Adsorption
Adsorption 工程技术-工程:化工
CiteScore
8.10
自引率
3.00%
发文量
18
审稿时长
2.4 months
期刊介绍: The journal Adsorption provides authoritative information on adsorption and allied fields to scientists, engineers, and technologists throughout the world. The information takes the form of peer-reviewed articles, R&D notes, topical review papers, tutorial papers, book reviews, meeting announcements, and news. Coverage includes fundamental and practical aspects of adsorption: mathematics, thermodynamics, chemistry, and physics, as well as processes, applications, models engineering, and equipment design. Among the topics are Adsorbents: new materials, new synthesis techniques, characterization of structure and properties, and applications; Equilibria: novel theories or semi-empirical models, experimental data, and new measurement methods; Kinetics: new models, experimental data, and measurement methods. Processes: chemical, biochemical, environmental, and other applications, purification or bulk separation, fixed bed or moving bed systems, simulations, experiments, and design procedures.
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