Addressing the persistence of per- and poly-fluoroalkyl substances (PFAS): current challenges and potential solutions

Emeka J. Itumoh, Shailja Data, Jack L.-Y. Chen, Melanie Kah, Lokesh P. Padhye and Erin M. Leitao
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Abstract

The combined stability, mobility, and bioaccumulation of per- and poly-fluoroalkyl substances (PFAS) has prompted a global environmental crisis. PFAS have unique properties owing to their strong, hydrophobic C–F bonds, which result in their resistance to water, oil, chemicals, and heat. Applications of PFAS include their use as water-, grease-, and fire-proof coatings, emulsifiers, and surfactants, spanning most manufacturing sectors. The continued regulation of specific PFAS provides significant research opportunities for chemists and their collaborators across environmental, social, engineering, and materials sciences. Solutions in the areas of detection and analysis, immobilisation and destruction, and the creation of viable and safe alternatives are urgently needed. In this tutorial review, PFAS and their associated challenges are described, followed by a summary of existing solutions and future research opportunities.

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解决全氟烷基和多氟烷基物质(PFAS)的持久性问题:当前的挑战和潜在的解决方案
全氟烷基和多氟烷基物质(PFAS)兼具稳定性、流动性和生物蓄积性,已引发全球环境危机。全氟辛烷磺酸具有独特的性质,因为它们具有很强的疏水性 C-F 键,从而具有耐水、耐油、耐化学品和耐热的特性。PFAS 的应用包括用作防水、防油和防火涂料、乳化剂和表面活性剂,遍及大多数制造行业。对特定 PFAS 的持续监管为化学家及其环境、社会、工程和材料科学领域的合作者提供了重要的研究机会。我们迫切需要在检测和分析、固定和销毁以及创造可行和安全的替代品方面找到解决方案。本教程综述介绍了全氟辛烷磺酸及其相关挑战,随后总结了现有的解决方案和未来的研究机会。
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Correction: Hydrothermal synthesis of ZnZrO x catalysts for CO2 hydrogenation to methanol: the effect of pH on structure and activity. Back cover Inside back cover Direct measurement of PFAS levels in surface water using an engineered biosensor. Statistical optimization of cell-hydrogel interactions for green microbiology - a tutorial review.
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