Effect of Magnetite on Compressive Strength of Concrete and Its Mechanism

IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Russian Journal of Physical Chemistry A Pub Date : 2024-09-09 DOI:10.1134/S003602442470122X
Xiaoxin Feng, Weihua Kang, Gang Liu, Ruiying Bai, Yukun An
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Abstract

The magnetite ore was taken as the partial aggregate to prepare two types of concrete specimens mixed with magnetite and without magnetite. Both were cured in water and 5 wt % Na2SO4 solution at 20 and 80°C, respectively, to study the influence on the strength of concrete. In addition, the magnetite ore was ground into powder, and cured in simulated concrete pore solution and 5 wt % Na2SO4 solution respectively, and the mineral and morphological change at different ages was tested by X-ray diffraction (XRD) and scanning electron microscope/energy dispersive spectrometer (SEM/EDS). The experimental results show that the strength of concrete with magnetite ore is a little higher than that of concrete without magnetite ore whether cured in water or in Na2SO4 solution, and the magnetite transforms into Fe2O3, ferrihydrite and other minerals in simulated concrete pore solution and in 5 wt % Na2SO4 solution. The experimental results also demonstrate that using some magnetite ore as aggregate for concrete is beneficial for improving the sulfate resistance of concrete.

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磁铁矿对混凝土抗压强度的影响及其机理
摘要 以磁铁矿为部分骨料,制备了掺有磁铁矿和不掺磁铁矿的两种混凝土试件。两种试样分别在 20°C 和 80°C 的水中和 5 wt % Na2SO4 溶液中养护,以研究其对混凝土强度的影响。此外,还将磁铁矿磨成粉末,分别在模拟混凝土孔隙溶液和 5 wt % Na2SO4 溶液中固化,并通过 X 射线衍射(XRD)和扫描电子显微镜/能量色散光谱仪(SEM/EDS)检测不同龄期的矿物和形态变化。实验结果表明,无论是在水中还是在 Na2SO4 溶液中养护,含磁铁矿的混凝土强度都比不含磁铁矿的混凝土强度略高,磁铁矿在模拟混凝土孔隙溶液和 5 wt % Na2SO4 溶液中转化为 Fe2O3、铁水物和其他矿物。实验结果还证明,使用某些磁铁矿作为混凝土骨料有利于提高混凝土的抗硫酸盐性能。
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来源期刊
CiteScore
1.20
自引率
14.30%
发文量
376
审稿时长
5.1 months
期刊介绍: Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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