{"title":"Chapter VI. Specificities of Hydrazine Ignition and Explosion as an Example of Anomalous Critical Phenomena","authors":"V. V. Azatyan","doi":"10.1134/S002315842460130X","DOIUrl":null,"url":null,"abstract":"<p>Based on the theory of nonisothermal chain reactions developed in the studies presented in the previous chapters, an experimentally verified explanation is given for the anomalous behavior of pyrolysis and combustion of a technically important product—hydrazine. The revealed kinetic features of N<sub>2</sub>H<sub>3</sub> radicals, which led to the unusual properties of the hydrazine-oxygen ignition peninsula, are also explained. The mechanism of easy ignition and explosion has been clarified.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S002315842460130X","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Based on the theory of nonisothermal chain reactions developed in the studies presented in the previous chapters, an experimentally verified explanation is given for the anomalous behavior of pyrolysis and combustion of a technically important product—hydrazine. The revealed kinetic features of N2H3 radicals, which led to the unusual properties of the hydrazine-oxygen ignition peninsula, are also explained. The mechanism of easy ignition and explosion has been clarified.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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