Effect of adsorption of different types of surfactants on conglomerate reservoir minerals on chemical oil recovery efficiency

IF 3.9 2区 工程技术 Q3 ENERGY & FUELS Geomechanics and Geophysics for Geo-Energy and Geo-Resources Pub Date : 2024-09-03 DOI:10.1007/s40948-024-00868-5
Xiaolong Yan, Yu Tian, Yongmin Shi, Xiaoguang Wang, Runxi Leng, Haoxuan Zheng, Shuai Zhao
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Abstract

Using surfactants to extract oil, the anionic surfactant Karamay petroleum sulfonate (KPS), the zwitterionic surfactant octadecyl betaine (BS-18) and the nonionic surfactant coconut oil fatty acid diethanolamide (6501) were selected for adsorption experiments with minerals contained in the conglomerate reservoir with different mineral compositions to study the adsorption law of different types of surfactants. Zeolite and montmorillonite, which have the highest specific surface area and zeta potential among the minerals in the conglomerate reservoir, have the most obvious adsorption effect on surfactants, resulting in a large amount of adsorption of KPS and BS-18. The three types of surfactants were then used to conduct physical simulation oil recovery experiments with conglomerate core samples, and the results showed that 6501 had better overall performance, the best adsorption resistance, and a higher degree of recovery in oil recovery experiments, which provided a basis for the selection of surfactants in the process of chemical drive in conglomerate reservoirs.

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不同类型表面活性剂在砾岩储层矿物上的吸附对化学采油效率的影响
利用表面活性剂采油,选择阴离子表面活性剂克拉玛依石油磺酸盐(KPS)、十八烷基甜菜碱(BS-18)和非离子表面活性剂椰油脂肪酸二乙醇酰胺(6501)与砾岩油藏中不同矿物组成的矿物进行吸附实验,研究不同类型表面活性剂的吸附规律。在砾岩储层矿物中,沸石和蒙脱石的比表面积和zeta电位最高,对表面活性剂的吸附作用最明显,导致KPS和BS-18的大量吸附。然后用这三种表面活性剂对砾岩岩心样品进行物理模拟采油实验,结果表明,6501的综合性能较好,吸附阻力最好,采油实验的采收率较高,为砾岩油藏化学驱过程中表面活性剂的选择提供了依据。
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来源期刊
Geomechanics and Geophysics for Geo-Energy and Geo-Resources
Geomechanics and Geophysics for Geo-Energy and Geo-Resources Earth and Planetary Sciences-Geophysics
CiteScore
6.40
自引率
16.00%
发文量
163
期刊介绍: This journal offers original research, new developments, and case studies in geomechanics and geophysics, focused on energy and resources in Earth’s subsurface. Covers theory, experimental results, numerical methods, modeling, engineering, technology and more.
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