Photochemistry of cyanoacetylene in solid argon revisited

IF 0.6 4区 物理与天体物理 Q4 PHYSICS, APPLIED Low Temperature Physics Pub Date : 2024-09-04 DOI:10.1063/10.0028163
Thomas G. Custer, Claudine Crépin, Marcin Gronowski, Arun-Libertsen Lawzer, Robert Kołos
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Abstract

Isotopic (2H and 15N) labelling and IR absorption spectroscopy have been used to study UV-induced transformations of cyanoacetylene in cryogenic noble gas matrices. The results obtained indicate that all observed isomerization processes involve single, isolated molecules of the precursor. No photoproducts have been found that would imply the recombination of fragments originating from different molecules.
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固态氩中氰乙炔的光化学再研究
利用同位素(2H 和 15N)标记和红外吸收光谱研究了紫外线诱导的氰乙炔在低温惰性气体基质中的转化。研究结果表明,所有观察到的异构化过程都涉及单个独立的前体分子。没有发现意味着来自不同分子的碎片重组的光产物。
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来源期刊
Low Temperature Physics
Low Temperature Physics 物理-物理:应用
CiteScore
1.20
自引率
25.00%
发文量
138
审稿时长
3 months
期刊介绍: Guided by an international editorial board, Low Temperature Physics (LTP) communicates the results of important experimental and theoretical studies conducted at low temperatures. LTP offers key work in such areas as superconductivity, magnetism, lattice dynamics, quantum liquids and crystals, cryocrystals, low-dimensional and disordered systems, electronic properties of normal metals and alloys, and critical phenomena. The journal publishes original articles on new experimental and theoretical results as well as review articles, brief communications, memoirs, and biographies. Low Temperature Physics, a translation of the copyrighted Journal FIZIKA NIZKIKH TEMPERATUR, is a monthly journal containing English reports of current research in the field of the low temperature physics. The translation began with the 1975 issues. One volume is published annually beginning with the January issues.
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