Di- and Octanuclear 1,2-Dimethylpyridinium and 3-Bromo-1-Ethylpyridinium Iodoantimonates(III): Crystal Structure and Physicochemical Properties

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Russian Journal of Inorganic Chemistry Pub Date : 2024-08-23 DOI:10.1134/s0036023624601156
I. A. Shentseva, K. A. Tagiltsev, A. N. Usol’tsev, N. A. Korobeynikov, V. R. Shayapov, M. N. Sokolov, S. A. Adonin
{"title":"Di- and Octanuclear 1,2-Dimethylpyridinium and 3-Bromo-1-Ethylpyridinium Iodoantimonates(III): Crystal Structure and Physicochemical Properties","authors":"I. A. Shentseva, K. A. Tagiltsev, A. N. Usol’tsev, N. A. Korobeynikov, V. R. Shayapov, M. N. Sokolov, S. A. Adonin","doi":"10.1134/s0036023624601156","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>New antimony complexes, (3-Br-1-EtPy)<sub>3</sub>[Sb<sub>2</sub>I<sub>9</sub>] (<b>1</b>) and (1,2-Me<sub>2</sub>Py)<sub>4</sub>[Sb<sub>8</sub>I<sub>28</sub>] (<b>2</b>) have been prepared by the reaction of SbI<sub>3</sub> with iodides of the corresponding cations in organic solvents. The features of the crystal structure of the compounds have been determined by X-ray diffraction. The complexes are thermally stable at least up to 200°C and have a band gap of ~2.2 eV.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"5 1","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s0036023624601156","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

New antimony complexes, (3-Br-1-EtPy)3[Sb2I9] (1) and (1,2-Me2Py)4[Sb8I28] (2) have been prepared by the reaction of SbI3 with iodides of the corresponding cations in organic solvents. The features of the crystal structure of the compounds have been determined by X-ray diffraction. The complexes are thermally stable at least up to 200°C and have a band gap of ~2.2 eV.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
二核和八核 1,2-二甲基吡啶鎓和 3-溴-1-乙基吡啶鎓碘锑酸盐(III):晶体结构和理化性质
摘要 通过 SbI3 与相应阳离子的碘化物在有机溶剂中的反应,制备了新的锑配合物 (3-Br-1-EtPy)3[Sb2I9] (1) 和 (1,2-Me2Py)4[Sb8I28] (2)。化合物晶体结构的特征已通过 X 射线衍射测定。这些复合物的热稳定性至少可达 200°C,带隙约为 2.2 eV。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
期刊最新文献
Luminescence Features of Multicomponent Cubic Fluoride Pyrochlores Doped with Europium Ions Synthesis and Thermodynamic Properties of Thulium Titanate Carboxonium Derivatives of closo-Decaborate Anion [2,6-B10H8O2CC6H4R]– Based on Aromatic Carboxylic Acids: Synthesis and Physicochemical Properties Isotope Effect in IR Spectra of Highly Enriched Amorphous Silicon Dioxide ASiO2 (A = 28, 29, 30) Synthesis, Crystal Structure, and Thermodynamic Properties of Ca3Y2Ge3O12
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1