Arumugam Suryaprakash, A. Ramar, Fu Ming Wang, Kefyalew Wagari Guji, Citra Deliana Dewi Sundari, Laurien Merinda
{"title":"Tautomerism and Nucleophilic Addition Influenced Performance on Aqueous Organic Redox Flow Batteries of Chelidamic Acid and Chelidonic Acid","authors":"Arumugam Suryaprakash, A. Ramar, Fu Ming Wang, Kefyalew Wagari Guji, Citra Deliana Dewi Sundari, Laurien Merinda","doi":"10.1039/d4ya00331d","DOIUrl":null,"url":null,"abstract":"The redox flow battery is a cost-effective solution for grid-scale energy storage. Its special feature of separate reservoirs and electrodes makes it easy to adjust electrolyte volume and electrode size, improving safety and scalability. In this work, we explore two organic anolytes, chelidamic acid (CDA) and chelidonic acid (CDO), which share similar molecular weight but differ in their heteroatoms: pyridone and pyrone. The half-cell potentials of CDA and CDO anolytes enable them to exhibit theoretical cell voltages of 0.49 V and 0.48 V, respectively, when coupled with K_4 [Fe^II (CN)_6] catholyte. CDA demonstrated a stable discharge capacity of 650 mAh/L over 17 days in a basic medium without any degradation. In contrast, CDO gradually lose its capacity over successive cycles. The mechanism for the decomposition of CDO was analysed through cyclic voltammetry, 1H-NMR, and FTIR spectroscopy techniques. The analytical results revealed that there was a significant impact of tautomerization in CDA and nucleophilic addition in CDO on the performance in ARFB.","PeriodicalId":72913,"journal":{"name":"Energy advances","volume":null,"pages":null},"PeriodicalIF":3.2000,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy advances","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/d4ya00331d","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The redox flow battery is a cost-effective solution for grid-scale energy storage. Its special feature of separate reservoirs and electrodes makes it easy to adjust electrolyte volume and electrode size, improving safety and scalability. In this work, we explore two organic anolytes, chelidamic acid (CDA) and chelidonic acid (CDO), which share similar molecular weight but differ in their heteroatoms: pyridone and pyrone. The half-cell potentials of CDA and CDO anolytes enable them to exhibit theoretical cell voltages of 0.49 V and 0.48 V, respectively, when coupled with K_4 [Fe^II (CN)_6] catholyte. CDA demonstrated a stable discharge capacity of 650 mAh/L over 17 days in a basic medium without any degradation. In contrast, CDO gradually lose its capacity over successive cycles. The mechanism for the decomposition of CDO was analysed through cyclic voltammetry, 1H-NMR, and FTIR spectroscopy techniques. The analytical results revealed that there was a significant impact of tautomerization in CDA and nucleophilic addition in CDO on the performance in ARFB.