You-Hui Tang, Peng Chen, Jin Yin, Jianghuan Shi, Yi-Jun Jiang
{"title":"Solvent-Controlled Divergent Synthesis of Thiocyanated Carbazoles and Di/Triphenylamines","authors":"You-Hui Tang, Peng Chen, Jin Yin, Jianghuan Shi, Yi-Jun Jiang","doi":"10.1055/a-2378-4540","DOIUrl":null,"url":null,"abstract":"<p>A solvent-controlled divergent thiocyanation of carbazoles and di/triphenylamines has been developed. Using either CH<sub>3</sub>CN/H<sub>2</sub>O (3:1) or DMSO as the solvent, a facile and efficient protocol for the solvent-controlled divergent synthesis of mono- and di-thiocyanation of carbazoles and di/triphenylamines was achieved. The salient features of this transformation include simple and mild reaction conditions, easily available substrates, and broad substrate scope.</p> ","PeriodicalId":501298,"journal":{"name":"Synthesis","volume":"31 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1055/a-2378-4540","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A solvent-controlled divergent thiocyanation of carbazoles and di/triphenylamines has been developed. Using either CH3CN/H2O (3:1) or DMSO as the solvent, a facile and efficient protocol for the solvent-controlled divergent synthesis of mono- and di-thiocyanation of carbazoles and di/triphenylamines was achieved. The salient features of this transformation include simple and mild reaction conditions, easily available substrates, and broad substrate scope.
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