Facile synthesis of copper sulfide loaded mesoporous organosilica nanospheres with a triple-shelled hollow structure

IF 2.5 4区 材料科学 Q2 CHEMISTRY, APPLIED Journal of Porous Materials Pub Date : 2024-08-22 DOI:10.1007/s10934-024-01668-8
Xuzhi Shi, Yifeng Yu, Ruifa Yu, Ning Wang, Wei Lu, Xiaolin Han, Tangyao Sun, Pengcheng Li, Xiaodan Su, Zhaogang Teng, Ying Liu
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Abstract

Herein, copper sulfide loaded mesoporous organosilica nanospheres with a triple-shelled hollow structure (CuS/tHMONs) are successfully synthesized. The resulting CuS/tHMONs nanospheres exhibit a uniform diameter of 340 nm, mesoporous channels with a diameter of 3.8 nm, large pore volume, and triply separated cavities. High-angle annular dark-field scanning electron microscopy (HAADF-STEM) images confirm the presence of a high content of CuS nanoparticles within the CuS/tHMONs composite nanospheres. Moreover, the CuS/tHMONs nanospheres demonstrate high photothermal conversion efficiency and excellent photothermal stability. In vitro experiments reveal excellent biocompatibility of the CuS/tHMON nanospheres, and cytotoxic assays demonstrate their effectiveness in killing cancer cells through photothermal therapy.

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硫化铜负载介孔有机硅纳米球三重壳中空结构的简便合成
本文成功合成了具有三壳中空结构的硫化铜负载介孔有机硅纳米球(CuS/tHMONs)。所制得的 CuS/tHMONs 纳米球直径均匀为 340 nm,介孔通道直径为 3.8 nm,孔体积大,空腔三重分离。高角度环形暗场扫描电子显微镜(HAADF-STEM)图像证实了 CuS/tHMONs 复合纳米球中存在大量的 CuS 纳米颗粒。此外,CuS/tHMONs 纳米球还具有很高的光热转换效率和出色的光热稳定性。体外实验表明,CuS/tHMONs 纳米球具有良好的生物相容性,细胞毒性实验也证明了它们在通过光热疗法杀死癌细胞方面的有效性。
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来源期刊
Journal of Porous Materials
Journal of Porous Materials 工程技术-材料科学:综合
CiteScore
4.80
自引率
7.70%
发文量
203
审稿时长
2.6 months
期刊介绍: The Journal of Porous Materials is an interdisciplinary and international periodical devoted to all types of porous materials. Its aim is the rapid publication of high quality, peer-reviewed papers focused on the synthesis, processing, characterization and property evaluation of all porous materials. The objective is to establish a unique journal that will serve as a principal means of communication for the growing interdisciplinary field of porous materials. Porous materials include microporous materials with 50 nm pores. Examples of microporous materials are natural and synthetic molecular sieves, cationic and anionic clays, pillared clays, tobermorites, pillared Zr and Ti phosphates, spherosilicates, carbons, porous polymers, xerogels, etc. Mesoporous materials include synthetic molecular sieves, xerogels, aerogels, glasses, glass ceramics, porous polymers, etc.; while macroporous materials include ceramics, glass ceramics, porous polymers, aerogels, cement, etc. The porous materials can be crystalline, semicrystalline or noncrystalline, or combinations thereof. They can also be either organic, inorganic, or their composites. The overall objective of the journal is the establishment of one main forum covering the basic and applied aspects of all porous materials.
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Correction: One-step synthesis of CuO/MCM-41 nanocomposites and their application in photocatalytic degradation of dyes Modification of SBA-15 for stabilizing supported oxides Lotus leaf-derived capacitive carbon for zinc-ion hybrid supercapacitors prepared by one-step molten salt carbonization Influence of various templates on the performance of MFI zeolite in catalytic synthesis of trioxane Facile synthesis of copper sulfide loaded mesoporous organosilica nanospheres with a triple-shelled hollow structure
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