{"title":"Medium engineering of lipase-catalyzed reaction using CO2","authors":"Tomoko Matsuda, Hai Nam Hoang","doi":"10.1002/aocs.12895","DOIUrl":null,"url":null,"abstract":"<p>One of the most frequently used biocatalysts for organic synthesis is lipase, a triacylglycerol hydrolase, that also catalyzes esterification in non-aqueous solvents. Various non-aqueous solvents such as organic solvents, ionic liquids, and pressurized carbon dioxide (CO<sub>2</sub>) have been employed for lipase-catalyzed reactions. Notably, pressurized CO<sub>2</sub> (supercritical CO<sub>2</sub>, liquid CO<sub>2</sub>, CO<sub>2</sub>-expanded liquid) serves as a functional green solvent. This review briefly outlines the properties of pressurized CO<sub>2</sub> relevant to biocatalysis and provides examples of utilizing pressurized CO<sub>2</sub> solvents for efficient synthesis with immobilized lipases.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 2","pages":"401-412"},"PeriodicalIF":1.9000,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Oil Chemists Society","FirstCategoryId":"97","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aocs.12895","RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
One of the most frequently used biocatalysts for organic synthesis is lipase, a triacylglycerol hydrolase, that also catalyzes esterification in non-aqueous solvents. Various non-aqueous solvents such as organic solvents, ionic liquids, and pressurized carbon dioxide (CO2) have been employed for lipase-catalyzed reactions. Notably, pressurized CO2 (supercritical CO2, liquid CO2, CO2-expanded liquid) serves as a functional green solvent. This review briefly outlines the properties of pressurized CO2 relevant to biocatalysis and provides examples of utilizing pressurized CO2 solvents for efficient synthesis with immobilized lipases.
期刊介绍：
The Journal of the American Oil Chemists’ Society (JAOCS) is an international peer-reviewed journal that publishes significant original scientific research and technological advances on fats, oils, oilseed proteins, and related materials through original research articles, invited reviews, short communications, and letters to the editor. We seek to publish reports that will significantly advance scientific understanding through hypothesis driven research, innovations, and important new information pertaining to analysis, properties, processing, products, and applications of these food and industrial resources. Breakthroughs in food science and technology, biotechnology (including genomics, biomechanisms, biocatalysis and bioprocessing), and industrial products and applications are particularly appropriate.
JAOCS also considers reports on the lipid composition of new, unique, and traditional sources of lipids that definitively address a research hypothesis and advances scientific understanding. However, the genus and species of the source must be verified by appropriate means of classification. In addition, the GPS location of the harvested materials and seed or vegetative samples should be deposited in an accredited germplasm repository. Compositional data suitable for Original Research Articles must embody replicated estimate of tissue constituents, such as oil, protein, carbohydrate, fatty acid, phospholipid, tocopherol, sterol, and carotenoid compositions. Other components unique to the specific plant or animal source may be reported. Furthermore, lipid composition papers should incorporate elements of yeartoyear, environmental, and/ or cultivar variations through use of appropriate statistical analyses.
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