Catalytic Ignition of Deuterium–Air Mixtures Over a Metallic Rhodium Surface at Pressures of 1–2 ATM

Abstract

The patterns of catalytic ignition of deuterium–air mixtures above the surface of metallic rhodium at pressures of 1–2 atm and temperatures of 20–250°C using hyperspectrometers in the range of 400–1650 nm and high-speed filming have been established. It is established that the catalytic ignition of deuterium–air mixtures in the studied temperature range is observed at a deuterium content of more than 12%; and at a deuterium content of less than 12%, only intense heating of the catalytic wire is observed. It is shown that the initial ignition source occurs on the surface of the reactor. In subsequent experiments, under the same conditions, the location of the original center changes. It has been found that the upper limit of the catalytic ignition above the D₂–air mixture is noticeably lower than the lower ignition limit of the H₂–air mixture. Thus, D₂ is more combustible than H₂ over the surface of Rh at a pressure above 1 atm. The limits of catalytic ignition are even lower than 20°C, although the flame velocity in hydrogen–air mixtures and the flame temperature in these mixtures of the same composition are much higher than those of deuterium–air mixtures. The nature of the detected kinetic inverse isotope effect is probably determined by the high level of activity of rhodium deuteride in relation to the deuterium oxidation reaction.