Combustion Peculiarities in the 2Co–Ti–Al System and Properties of the Half-Metallic Ferromagnetic Heusler Alloy Co2TiAl

IF 1.4 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL Russian Journal of Physical Chemistry B Pub Date : 2024-09-11 DOI:10.1134/s1990793124700544
M. L. Busurina, A. E. Sytschev, S. G. Vadchenko, A. V. Karpov
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Abstract

Combustion in the 2Co–Ti–Al system is observed by high-speed video recording. It is established that combustion occurs in the frontal mode, and the process parameters are determined. The maximum rate of the increase in the combustion temperature from the moment of initiation to the maximum value reached is 2.7 × 104 K/s. The front propagation velocity calculated from the video recording is 9.4 cm/s. The microhotspot mode of combustion of the reaction composition is found. The temperature dependencies of the electrical resistivity and magnetic moment of the single-phase Co2TiAl product synthesized in the combustion mode are measured. For the synthesized Co2TiAl sample, the Curie temperature is TC = 120 ± 5 K and the electrical resistivity at room temperature is 1.35 μOhm m. It is shown that the electrical and magnetic properties of the Co2TiAl alloy obtained in the combustion mode are similar to those of alloys obtained by arc melting.

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2Co-Ti-Al 系统的燃烧特异性和半金属铁磁 Heusler 合金 Co2TiAl 的性质
摘要 通过高速视频记录观察了 2Co-Ti-Al 系统中的燃烧。确定了燃烧是以正面模式进行的,并确定了过程参数。从开始燃烧到达到最大值,燃烧温度的最大上升率为 2.7 × 104 K/s。根据视频记录计算出的正面传播速度为 9.4 厘米/秒。发现了反应成分的微热点燃烧模式。测量了在燃烧模式下合成的单相 Co2TiAl 产物的电阻率和磁矩的温度依赖性。燃烧模式合成的 Co2TiAl 样品的居里温度为 TC = 120 ± 5 K,室温下的电阻率为 1.35 μOhm m。
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来源期刊
Russian Journal of Physical Chemistry B
Russian Journal of Physical Chemistry B 化学-物理:原子、分子和化学物理
CiteScore
2.20
自引率
71.40%
发文量
106
审稿时长
4-8 weeks
期刊介绍: Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
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