Integration of Samarium Vanadate/Halloysite Nanotubes: Electrochemical Determination of Furaltadone Using Flexible Electrode

Jayasmita Jana, Tata Sanjay Kanna Sharma, Beena Mol Babu, Sabah Ansar, Somnath Chowdhury, Balasubramanian Sriram, Sea-Fue Wang, Sung Gu Kang, Jin Suk Chung, Won Mook Choi, Seung Hyun Hur
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Abstract

In this study, a composite comprising a rare-earth metal, samarium vanadate (SmVO4, SmV), anchored to halloysite nanotube (HNT) making SmV/HNT nanocomposite is synthesized for the sensitive electrochemical determination of furaltadone (FLD) through differential pulse voltammetry analysis based on the synergistic effect of SmV/HNT (the catalytic activity and chemical stability of SmV, which was further boosted by the improved surface area and conductance of HNT). Further, in the microscopic studies, it is revealed that SmV exhibits a tetragonal zircon-type crystalline structure, with I41/amd (141) space group, whereas HNT comprises a multiphase kaolin composition as a gibbsite-like octahedral sheet with multivalency, and the morphological irregularities of the individual constituents are rectified in the composite. The SmV/HNT composite is spray-coated on polyethylene terephthalate sheet, which delivered a promising trace level limit of detection (0.009 μm) over a wide working range (0.05–194.4 μm) for FLD. Furthermore, real sample analysis is performed using human serum, and pharmaceutical tablet and the results reveal exceptional repeatability and sensitivity, indicating the real-time application of SmV/HNT in the pharmaceutical domain.

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集成钒酸钐/高合金纳米管:使用柔性电极电化学测定呋喃他酮
在本研究中,基于 SmV/HNT 的协同效应(SmV 的催化活性和化学稳定性,通过 HNT 的比表面积和电导率的改善得到进一步提高),合成了一种由稀土金属钒酸钐(SmVO4,SmV)与霍洛石纳米管(HNT)组成的 SmV/HNT 纳米复合材料,用于通过差分脉冲伏安分析法对呋喃他酮(FLD)进行灵敏的电化学测定。此外,在显微研究中还发现,SmV 呈四方锆石型晶体结构,具有 I41/amd (141) 空间群,而 HNT 则由多相高岭土成分组成,是具有多价性的长臂石状八面体片材,复合材料中各成分的形态不规则性得到了纠正。SmV/HNT 复合材料喷涂在聚对苯二甲酸乙二醇酯薄片上,在 FLD 的宽工作范围(0.05-194.4 μm)内实现了良好的痕量检测限(0.009 μm)。此外,还利用人体血清和药片进行了实际样品分析,结果表明该方法具有优异的重复性和灵敏度,表明 SmV/HNT 可实时应用于制药领域。
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