Synthesis and Structure of 4-[(anthracene-9′-ylmethylene)amino]-5-R-2,4-Dihydro-3H-1,2,4-Triazole-3-Thiones

IF 1.2 4区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Journal of Structural Chemistry Pub Date : 2024-09-04 DOI:10.1134/S0022476624080146
A. A. Kolodina, O. P. Demidov, L. D. Popov, I. V. Dubonosova, E. S. Khodykina, A. V. Skorova, S. B. Zaichenko, I. G. Borodkina, A. D. Dubonosov, A. V. Metelitsa, V. G. Vlasenko
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Abstract

By the condensation of 4-amino-5-R-2,4-dihydro-3H-1,2,4-triazole-3-thiones with anthracene-9- carbaldehyde, respective 4-[(anthracene-9′-ylmethylene)amine)]-5-R-2,4-dihydro-3H-1,2,4-triazole-3-thiones are prepared and structurally characterized by NMR, UV, IR spectroscopies, high-resolution mass spectrometry, and single crystal XRD. The effect of a substituent at position 5 in triazole moieties of azomethines obtained on their head-to-head or head-to-tail crystal packings is determined.

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4-[(蒽-9′-亚甲基)氨基]-5-R-2,4-二氢-3H-1,2,4-三唑-3-硫酮的合成与结构
摘要 通过 4-氨基-5-R-2,4-二氢-3H-1,2,4-三唑-3-硫酮与蒽-9-甲醛的缩合,制备了相应的 4-[(蒽-9′-基亚甲基)胺)]-5-R-2,4-二氢-3H-1,2,4-三唑-3-硫酮,并通过核磁共振、紫外、红外光谱、高分辨质谱和单晶 XRD 对其结构进行了表征。研究还确定了偶氮甲烷三唑分子中第 5 位取代基对其头对头或头对尾晶体包合的影响。
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来源期刊
Journal of Structural Chemistry
Journal of Structural Chemistry 化学-无机化学与核化学
CiteScore
1.60
自引率
12.50%
发文量
142
审稿时长
8.3 months
期刊介绍: Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
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