{"title":"High-temperature corrosion of nanocrystalline Ni with varying grain sizes in FLiNaK salt and corrosion-induced surface faceting","authors":"","doi":"10.1016/j.surfin.2024.105052","DOIUrl":null,"url":null,"abstract":"<div><p>Nanocrystalline nickel (NC<img>Ni) coatings are currently under investigation to enhance the corrosion resistance of structural components in molten salt reactors (MSRs). The corrosion behavior of NC<img>Ni with varying grain sizes of 20 nm, 100 nm and 200 nm in a FLiNaK environment is studied. Interestingly, as the grain size increases, there is a systematic increase in weight loss. Studies conducted using electron backscattered diffraction (EBSD) on corrosion-tested and annealed samples revealed the significant role played by various microstructural attributes in enhancing corrosion resistance. These attributes include 〈100〉 crystallographic orientation, a high fraction of twin boundaries, low random boundary connectivity, high J<sub>2</sub>/(1-J<sub>3</sub>) value and low grain boundary length per area. The NC<img>Ni with the 20 nm grain size showed exceptional corrosion resistance due to a higher prevalence of these attributes. Furthermore, corrosion-induced facets, such as pyramids, terraces, steps, etc., are observed for the first time in FLiNaK solution, with grain interiors and boundaries exhibiting various morphologies. The impurities from the salt result in surface anisotropy leading to surface reconstruction and formation of facets. The study presents new findings that are significant for the MSR community: in systems where the protective oxide layer dissolves readily and lacks sustainability in the corroding medium, all the above-mentioned microstructural attributes are vital. Their predominance leads to enhanced corrosion resistance.</p></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":null,"pages":null},"PeriodicalIF":5.7000,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surfaces and Interfaces","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2468023024012082","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Nanocrystalline nickel (NCNi) coatings are currently under investigation to enhance the corrosion resistance of structural components in molten salt reactors (MSRs). The corrosion behavior of NCNi with varying grain sizes of 20 nm, 100 nm and 200 nm in a FLiNaK environment is studied. Interestingly, as the grain size increases, there is a systematic increase in weight loss. Studies conducted using electron backscattered diffraction (EBSD) on corrosion-tested and annealed samples revealed the significant role played by various microstructural attributes in enhancing corrosion resistance. These attributes include 〈100〉 crystallographic orientation, a high fraction of twin boundaries, low random boundary connectivity, high J2/(1-J3) value and low grain boundary length per area. The NCNi with the 20 nm grain size showed exceptional corrosion resistance due to a higher prevalence of these attributes. Furthermore, corrosion-induced facets, such as pyramids, terraces, steps, etc., are observed for the first time in FLiNaK solution, with grain interiors and boundaries exhibiting various morphologies. The impurities from the salt result in surface anisotropy leading to surface reconstruction and formation of facets. The study presents new findings that are significant for the MSR community: in systems where the protective oxide layer dissolves readily and lacks sustainability in the corroding medium, all the above-mentioned microstructural attributes are vital. Their predominance leads to enhanced corrosion resistance.
期刊介绍:
The aim of the journal is to provide a respectful outlet for ''sound science'' papers in all research areas on surfaces and interfaces. We define sound science papers as papers that describe new and well-executed research, but that do not necessarily provide brand new insights or are merely a description of research results.
Surfaces and Interfaces publishes research papers in all fields of surface science which may not always find the right home on first submission to our Elsevier sister journals (Applied Surface, Surface and Coatings Technology, Thin Solid Films)