Achieving fine tailoring of elastocaloric properties of laser powder bed-fused NiTi alloy via laser beam manipulation

Abstract

Laser powder bed fusion (LPBF) technology enables the development of NiTi alloys with complex geometries and tunable phase-transformation temperatures (PTTs). This technology is increasingly acknowledged as promising in the field of elastocaloric (eC) refrigeration. However, the mechanisms governing the manner in which this technology tunes the eC performance remain ambiguous. This study evaluated the fine-tuning of the eC properties by regulating Ni evaporation through laser manipulation. Our results demonstrate that although adjusting Ni loss via laser heat input can effectively control the PTTs, inappropriate combinations of laser parameters may result in lower than anticipated cooling capacity (ΔT_ad) and coefficient of performance (COP_mat) of produced samples. An excessive heat input results in Ni evaporation and in grain coarsening through the remelting and combination of fine grains owing to overlapping molten pools. Lower Ni enhances the phase-transformation enthalpy (ΔH_tr). However, larger grains increase the energy dissipation and thereby, counteracting ΔT_ad improvements. Theoretical analysis and experiments revealed that finer grains increase the misorientation angles. This hinders the dislocation motion and thereby, enhances the mechanical properties. Meanwhile, coarser grains can more conveniently promote PT and thereby, increase ΔH_tr. Thus, based on the naturally controllable grain size heterogeneity in LPBF-manufactured NiTi alloys, we propose optimizing the eC properties by controlling the morphology of the molten pool. Thermal-history simulations could balance this relationship. Ultimately, we developed two NiTi alloys for both high-temperature (70 °C) and room-temperature (25 °C) refrigeration. This study has provided effective insights for customizing high-performance eC components such as multistage caloric cascade regenerators, using additive manufacturing.