{"title":"Upcycling sugar beet waste into sustainable organo-nanocatalysis for carbon dioxide fixation and cyclic carbonate synthesis: a research design study","authors":"Fateme Moazen, Hossein Eshghi, Hossein Torabi","doi":"10.1186/s40712-024-00178-4","DOIUrl":null,"url":null,"abstract":"<div><p>Environmental pollution is a major global issue due to the increase of various pollutants all over the world. Enhancing pollutant remediation strategies for environmental sustainability necessitates increasing the efficiency of conventional methods or introducing innovative approaches. Nanotechnology, particularly carbon-based nanomaterials, offers substantial promise due to their high surface area and absorption potential. Concurrently, organocatalysts have emerged as sustainable and versatile alternatives to traditional metal-based catalysts in modern chemical research. This study highlights the synthesis and application of organo-nanocatalysts derived from biomass, specifically a spherical carbon nanocatalyst synthesized from sugar beet pulp. This novel green catalyst, characterized by high selectivity and efficiency, successfully converts epoxides and CO<sub>2</sub> into valuable cyclic carbonates under solvent-free conditions. The hydroxyl groups on the Sugar Beet-derived Carbon NanoSphere (SCNS) surface act as Bronsted acid sites, facilitating epoxide activation via hydrogen bonding. The integration of carbon-based nanomaterials and organocatalysis represents a promising, sustainable solution for pollutant remediation and green chemistry advancements.</p><h3>Graphical Abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4000,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00178-4","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mechanical and Materials Engineering","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1186/s40712-024-00178-4","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Environmental pollution is a major global issue due to the increase of various pollutants all over the world. Enhancing pollutant remediation strategies for environmental sustainability necessitates increasing the efficiency of conventional methods or introducing innovative approaches. Nanotechnology, particularly carbon-based nanomaterials, offers substantial promise due to their high surface area and absorption potential. Concurrently, organocatalysts have emerged as sustainable and versatile alternatives to traditional metal-based catalysts in modern chemical research. This study highlights the synthesis and application of organo-nanocatalysts derived from biomass, specifically a spherical carbon nanocatalyst synthesized from sugar beet pulp. This novel green catalyst, characterized by high selectivity and efficiency, successfully converts epoxides and CO2 into valuable cyclic carbonates under solvent-free conditions. The hydroxyl groups on the Sugar Beet-derived Carbon NanoSphere (SCNS) surface act as Bronsted acid sites, facilitating epoxide activation via hydrogen bonding. The integration of carbon-based nanomaterials and organocatalysis represents a promising, sustainable solution for pollutant remediation and green chemistry advancements.