Liquid–Liquid Equilibria Data and Thermodynamic Modeling of {Mesityl Oxide + Diethoxymethane + Water} Ternary System at 303.15, 313.15, 323.15 K Under 101.325 kPa

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-09-19 DOI:10.1007/s10953-024-01398-0
Hongyue Guo, Tao Li, Qingsong Li, Zhongtao Li
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Abstract

The liquid–liquid equilibrium (LLE) of the mesityl oxide + diethoxymethane + water was determined at 303.15, 313.15 and 323.15 K under 101.325 kPa, which was consistent with the Treybal’s type II ternary phase behavior. The distribution coefficients (D) and selectivity coefficients (S) were used to evaluate the extraction ability of mesityl oxide to extract diethoxymethane from water. The experimental data were correlated with the NRTL and UNIQUAC thermodynamic models, and the RMSD values are both less than 0.47%, indicating that the two models can well correlate the experimental data.

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在 303.15、313.15、323.15 K 和 101.325 kPa 下{氧化甲酯 + 二乙氧基甲烷 + 水}三元体系的液液平衡数据和热力学模型
在 303.15、313.15 和 323.15 K(101.325 kPa)条件下测定了氧化甲硅烷+二乙氧基甲烷+水的液液平衡(LLE),结果与 Treybal 的 II 型三元相行为一致。分配系数(D)和选择性系数(S)用于评估氧化甲硅烷从水中萃取二乙氧基甲烷的能力。实验数据与 NRTL 和 UNIQUAC 热力学模型进行了相关性分析,其 RMSD 值均小于 0.47%,表明这两个模型能够很好地对实验数据进行相关性分析。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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