{"title":"Synthesis and Reactivity of the Amino-Functionalized β-Diketiminate Ligand Stabilized Germylene and Stannylene","authors":"Tianyi Sun, Cheng Kong, Linlin Wu, Hao Wang","doi":"10.1002/ejic.202400378","DOIUrl":null,"url":null,"abstract":"<p>Amino-functionalized β-diketiminate stabilized chlorogermylene <b>1</b> and chlorostannylene <b>2</b> have been prepared and structurally characterized. The reactions of <b>1</b> or <b>2</b> with KO<sup><i>t</i></sup>Bu afforded the β-diketiminate stabilized <i>tert</i>-butoxygermylene <b>3</b> and <i>tert</i>-butoxystannylene <b>4</b>, respectively. On the other hand, the reaction of <b>2</b> with LiN(SiMe<sub>3</sub>)<sub>2</sub> led to the isolation of the bis-stannylene <b>5</b> containing a four-membered Sn<sub>2</sub>N<sub>2</sub> ring. All new compounds have been characterized by multiple NMR spectroscopy and single crystal X-ray analysis.</p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"27 33","pages":""},"PeriodicalIF":2.2000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Inorganic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202400378","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Amino-functionalized β-diketiminate stabilized chlorogermylene 1 and chlorostannylene 2 have been prepared and structurally characterized. The reactions of 1 or 2 with KOtBu afforded the β-diketiminate stabilized tert-butoxygermylene 3 and tert-butoxystannylene 4, respectively. On the other hand, the reaction of 2 with LiN(SiMe3)2 led to the isolation of the bis-stannylene 5 containing a four-membered Sn2N2 ring. All new compounds have been characterized by multiple NMR spectroscopy and single crystal X-ray analysis.
期刊介绍：
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
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