O. N. Fedyaeva, A. P. Grebennikov, A. A. Vostrikov
{"title":"Features of Oxidation of Bismuth by High-Density Water-Oxygen Fluid","authors":"O. N. Fedyaeva, A. P. Grebennikov, A. A. Vostrikov","doi":"10.1134/S1810232824030020","DOIUrl":null,"url":null,"abstract":"<p>The paper presents the results of a study of oxidation of bulk bismuth samples by oxygen, water vapor, and water-oxygen fluid in a reactor heated to 873 K at a rate of 1 K/min with high-density reagents (<span>\\(\\rho_{{\\rm O_{2}}}\\le0.62\\)</span> and <span>\\(\\rho_{{\\rm H_{2}O}}\\le5.24\\)</span> mol/dm<sup>3</sup>). The results include temperature dependences of the pressure of the reaction mixtures. The rate of oxygen consumption is found from these dependences through the Redlich–Kwong equation of state. Formation of dense oxide film during the oxidation of bismuth in the O<sub>2</sub> environment was shown. No oxide formation was detected during treatment of bismuth with water vapor. The combined action of O<sub>2</sub> and H<sub>2</sub>O molecules enhances the oxidation of bismuth and leads to formation of oxides of different compositions and morphologies. At <span>\\(T>720\\)</span> K, the bismuth oxidation rate was observed to increase due to the higher pressure of saturated bismuth vapor.</p>","PeriodicalId":627,"journal":{"name":"Journal of Engineering Thermophysics","volume":"33 3","pages":"467 - 477"},"PeriodicalIF":1.3000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Engineering Thermophysics","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S1810232824030020","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, MECHANICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The paper presents the results of a study of oxidation of bulk bismuth samples by oxygen, water vapor, and water-oxygen fluid in a reactor heated to 873 K at a rate of 1 K/min with high-density reagents (\(\rho_{{\rm O_{2}}}\le0.62\) and \(\rho_{{\rm H_{2}O}}\le5.24\) mol/dm3). The results include temperature dependences of the pressure of the reaction mixtures. The rate of oxygen consumption is found from these dependences through the Redlich–Kwong equation of state. Formation of dense oxide film during the oxidation of bismuth in the O2 environment was shown. No oxide formation was detected during treatment of bismuth with water vapor. The combined action of O2 and H2O molecules enhances the oxidation of bismuth and leads to formation of oxides of different compositions and morphologies. At \(T>720\) K, the bismuth oxidation rate was observed to increase due to the higher pressure of saturated bismuth vapor.
期刊介绍：
Journal of Engineering Thermophysics is an international peer reviewed journal that publishes original articles. The journal welcomes original articles on thermophysics from all countries in the English language. The journal focuses on experimental work, theory, analysis, and computational studies for better understanding of engineering and environmental aspects of thermophysics. The editorial board encourages the authors to submit papers with emphasis on new scientific aspects in experimental and visualization techniques, mathematical models of thermophysical process, energy, and environmental applications. Journal of Engineering Thermophysics covers all subject matter related to thermophysics, including heat and mass transfer, multiphase flow, conduction, radiation, combustion, thermo-gas dynamics, rarefied gas flow, environmental protection in power engineering, and many others.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
