A Study of Low Global Warming Potential Refrigerants to Replace R123 for Chiller Application

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-09-18 DOI:10.1134/S1810232824030147
L. Zhang, J. Zhao, L. Mu, H. Fang
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Abstract

The raising concern about climate change and global warming provides the searching for more environmental friendly refrigerants for chiller applications. In this study, an investigation for low GWP refrigerants to replace R123 has been conducted for evaluation for chiller systems. R1233zd(E), R1234ze(E), R1234yf, R290, and R600 have been compared with R123 under different effecting factors. R1233zd(E) and R600 display a close COP performance when compared with the baseline R123, while other R123 alternatives present a low COP level (more than 5% COP decrease from baseline R123). R290 displays the highest value of the compressor impeller speed while R123 the lowest. In general, R1233zd(E) is preferred for drop-in option to replace R123 due to close COP and unit capacity by volume. R1234ze(E), R1234yf, and R290 are preferred for chiller down-size options. Increasing evaporating temperature from 1°C to 5°C can display more than 15% COP enhancement and it does not have the significant change for the mass flow rate and the compressor impeller speed. The condensing temperature increase from 30°C to 40°C has significant influence on the system COP drop, with \(\sim30\)% COP decrease there. Increasing the compressor isentropic efficiency from 0.6 to 0.8 can make the COP increased by more than 30%, and make the compressor power consumption to be reduced by more than 24%. From the single-stage cycle chiller system to the two-stage cycle chiller system, the COP can be improved by 3.0% for R123, 3.1% for R1233zd(E), 4.4% for R1234ze(E), 5.1% for R1234yf, 4.0% for R290, and 3.5% for R600, respectively. In general, R1234yf is more sensitive for the cycle improvement.

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冷风机应用中替代 R123 的低全球升温潜能值制冷剂研究
摘要 对气候变化和全球变暖的日益关注,为冷风机应用提供了寻找更环保制冷剂的机会。本研究调查了可替代 R123 的低全球升温潜能值制冷剂,并对冷水机系统进行了评估。在不同的影响因素下,R1233zd(E)、R1234ze(E)、R1234yf、R290 和 R600 与 R123 进行了比较。与基准 R123 相比,R1233zd(E) 和 R600 的 COP 性能接近,而其他 R123 替代品的 COP 水平较低(与基准 R123 相比,COP 下降超过 5%)。R290 的压缩机叶轮速度值最高,而 R123 最低。一般来说,R1233zd(E) 由于 COP 和单位容量(体积)接近,是替代 R123 的首选。R1234ze (E)、R1234yf 和 R290 则是冷风机减小规模的首选。将蒸发温度从 1°C 提高到 5°C,可使 COP 提高 15%以上,但对质量流量和压缩机叶轮速度的影响不大。冷凝温度从 30°C 提高到 40°C 对系统 COP 下降有很大影响,COP 下降了 %。将压缩机等熵效率从 0.6 提高到 0.8 可以使 COP 提高 30%以上,并使压缩机功耗降低 24%以上。从单级循环冷水机系统到双级循环冷水机系统,R123 的 COP 可分别提高 3.0%、R1233zd(E) 的 COP 可分别提高 3.1%、R1234ze(E) 的 COP 可分别提高 4.4%、R1234yf 的 COP 可分别提高 5.1%、R290 的 COP 可分别提高 4.0%、R600 的 COP 可分别提高 3.5%。一般来说,R1234yf 对循环改善更为敏感。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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