New Double Complex Salts [M(im)n][RuNOCl5] (M = Ni, Cu): Synthesis, Structure, and Thermal Properties

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Russian Journal of Inorganic Chemistry Pub Date : 2024-09-15 DOI:10.1134/s003602362470058x
A. O. Borodin, E. Yu. Filatov, P. E. Plusnin, N. V. Kuratieva, S. V. Korenev, G. A. Kostin
{"title":"New Double Complex Salts [M(im)n][RuNOCl5] (M = Ni, Cu): Synthesis, Structure, and Thermal Properties","authors":"A. O. Borodin, E. Yu. Filatov, P. E. Plusnin, N. V. Kuratieva, S. V. Korenev, G. A. Kostin","doi":"10.1134/s003602362470058x","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Procedures for the synthesis of new double complex salts [Cu(im)<sub>4</sub>][RuNOCl<sub>5</sub>], [Ni(im)<sub>6</sub>][RuNOCl<sub>5</sub>]·H<sub>2</sub>O, and <i>p</i>-[Ni(im)<sub>4</sub>(DMF)<sub>2</sub>][RuNOCl<sub>5</sub>] have been developed and their crystal structure have been determined. Thermal properties of the synthesized DCS have been studied under inert and reducing atmospheres using synchronous TG–DTA and ex situ XRD of intermediate and final thermolysis products. It has been found that thermal decomposition occurs in three stages. Thermolysis of [Cu(im)<sub>4</sub>][RuNOCl<sub>5</sub>] under inert and reducing atmospheres gives rise to the mixture of copper and ruthenium, while the thermal decomposition of [Ni(im)<sub>6</sub>][RuNOCl<sub>5</sub>]·H<sub>2</sub>O under an inert atmosphere results in a mixture of nickel and ruthenium. A supersaturated Ni<sub>0.27</sub>Ru<sub>0.73</sub> solid solution can be obtained in the nickel-ruthenium system upon thermolysis under a reducing atmosphere at temperature up to 400°C. Increase in thermolysis temperature up to 800°C leads to the partial decomposition of the solid solution.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s003602362470058x","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

Procedures for the synthesis of new double complex salts [Cu(im)4][RuNOCl5], [Ni(im)6][RuNOCl5]·H2O, and p-[Ni(im)4(DMF)2][RuNOCl5] have been developed and their crystal structure have been determined. Thermal properties of the synthesized DCS have been studied under inert and reducing atmospheres using synchronous TG–DTA and ex situ XRD of intermediate and final thermolysis products. It has been found that thermal decomposition occurs in three stages. Thermolysis of [Cu(im)4][RuNOCl5] under inert and reducing atmospheres gives rise to the mixture of copper and ruthenium, while the thermal decomposition of [Ni(im)6][RuNOCl5]·H2O under an inert atmosphere results in a mixture of nickel and ruthenium. A supersaturated Ni0.27Ru0.73 solid solution can be obtained in the nickel-ruthenium system upon thermolysis under a reducing atmosphere at temperature up to 400°C. Increase in thermolysis temperature up to 800°C leads to the partial decomposition of the solid solution.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
新型双络合盐 [M(im)n][RuNOCl5](M = Ni、Cu):合成、结构和热性能
摘要 开发了合成新的双络合盐[Cu(im)4][RuNOCl5]、[Ni(im)6][RuNOCl5]-H2O 和 p-[Ni(im)4(DMF)2][RuNOCl5] 的方法,并确定了它们的晶体结构。利用同步 TG-DTA 和中间及最终热解产物的原位 XRD 研究了合成的 DCS 在惰性和还原气氛下的热性质。研究发现,热分解分为三个阶段。在惰性和还原气氛下,[Cu(im)4][RuNOCl5]的热分解产生铜和钌的混合物,而在惰性气氛下,[Ni(im)6][RuNOCl5]-H2O 的热分解产生镍和钌的混合物。镍-钌体系在还原气氛下进行热分解,温度最高可达 400°C,可得到过饱和的 Ni0.27Ru0.73 固溶体。热解温度升高至 800°C 会导致固溶体部分分解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
期刊最新文献
Luminescence Features of Multicomponent Cubic Fluoride Pyrochlores Doped with Europium Ions Synthesis and Thermodynamic Properties of Thulium Titanate Carboxonium Derivatives of closo-Decaborate Anion [2,6-B10H8O2CC6H4R]– Based on Aromatic Carboxylic Acids: Synthesis and Physicochemical Properties Isotope Effect in IR Spectra of Highly Enriched Amorphous Silicon Dioxide ASiO2 (A = 28, 29, 30) Synthesis, Crystal Structure, and Thermodynamic Properties of Ca3Y2Ge3O12
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1