Shale Oil Generation Conditions and Exploration Prospects of the Cretaceous Nenjiang Formation in the Changling Depression, Songliao Basin, China

IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Minerals Pub Date : 2024-09-15 DOI:10.3390/min14090942
Wenjun Zhang, Wenyu Zhang, Shumin Lin, Xing Ke, Min Zhang, Taohua He
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Abstract

Low-maturity shale oil predominates in shale oil resources. China’s onshore shale oil, particularly the Cretaceous Nenjiang Formation in the Songliao Basin, holds significant potential for low-maturity shale oil, presenting promising exploration and development prospects. This study delves into the hydrocarbon generation conditions, reservoir characteristics, and oil-bearing property analysis of the mud shale from the Nen-1 and Nen-2 sub-formations of the Nenjiang Formation to pinpoint favorable intervals for shale oil exploration. Through the integration of lithology, pressure, and fracture distribution data in the study area, favorable zones were delineated. The Nen-1 sub-formation is widely distributed in the Changling Depression, with mud shale thickness ranging from 30 to 100 m and a total organic content exceeding 2.0%. Type I kerogen predominated as the source rock, while some samples contained type II kerogen. Organic microcomponents primarily comprised algal bodies, with vitrinite reflectance (Ro) ranging from 0.5% to 0.8%. Compared to Nen-1 shale, Nen-2 shale exhibited less total organic content, kerogen type, and thermal evolution degree, albeit both are conducive to low-maturity shale oil generation. The Nen-1 and Nen-2 sub-formations predominantly consist of clay, quartz, feldspar, calcite, and pyrite minerals, with minor dolomite, siderite, and anhydrite. Hydrocarbons primarily reside in microfractures and micropores, including interlayer micropores, organic matter micropores, intra-cuticle micropores, and intercrystalline microporosity, with interlayer and intra-cuticle micropores being dominant. The free oil content (S1) in Nen-1 shale ranged from 0.01 mg/g to 5.04 mg/g (average: 1.13 mg/g), while in Nen-2 shale, it ranged from 0.01 mg/g to 3.28 mg/g (average: 0.75 mg/g). The Nen-1 and Nen-2 sub-formations are identified as potential intervals for shale oil exploration. Considering total organic content, oil saturation, vitrinite reflectance, and shale formation thickness in the study area, the favorable zone for low-maturity shale oil generation is primarily situated in the Heidimiao Sub-Depression and its vicinity. The Nen-2 shale-oil-enriched zone is concentrated in the northwest part of the Heidimiao Sub-Depression, while the Nen-1 shale-oil-enriched zone lies in the northeast part.
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中国松辽盆地长岭凹陷白垩系嫩江地层页岩油生成条件与勘探前景
页岩油资源中以低成熟页岩油为主。中国陆相页岩油,特别是松辽盆地白垩系嫩江地层蕴藏着巨大的低成熟页岩油潜力,勘探开发前景广阔。本研究深入探讨了嫩江地层嫩-1、嫩-2亚层泥页岩的生烃条件、储层特征和含油性质分析,以确定页岩油勘探的有利区间。通过整合研究区域的岩性、压力和裂缝分布数据,划定了有利区带。念-1 次构造在长岭凹陷分布广泛,泥页岩厚度在 30 至 100 米之间,总有机质含量超过 2.0%。源岩以I型角质为主,部分样品含有II型角质。有机微成分主要包括藻体,玻璃光泽反射率(Ro)介于 0.5% 至 0.8% 之间。与 "念-1 "页岩相比,"念-2 "页岩的总有机质含量、角质类型和热演化程度都较低,但都有利于低成熟度页岩油的生成。念-1 和念-2 亚地层主要由粘土、石英、长石、方解石和黄铁矿矿物组成,还有少量白云石、菱铁矿和无水石膏。碳氢化合物主要赋存在微裂隙和微孔中,包括层间微孔、有机质微孔、切晶内微孔和晶间微孔,其中以层间微孔和切晶内微孔为主。念-1 页岩的游离油含量(S1)介于 0.01 毫克/克至 5.04 毫克/克(平均:1.13 毫克/克)之间,而念-2 页岩的游离油含量(S1)介于 0.01 毫克/克至 3.28 毫克/克(平均:0.75 毫克/克)之间。念-1 和念-2 子地层被确定为页岩油勘探的潜在区间。考虑到研究区的总有机质含量、含油饱和度、玻璃光泽反射率和页岩层厚度,低成熟页岩油生成的有利区主要位于黑帝庙次凹陷及其附近。念-2页岩油富集区集中在黑帝庙次凹陷西北部,念-1页岩油富集区位于东北部。
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来源期刊
Minerals
Minerals MINERALOGY-MINING & MINERAL PROCESSING
CiteScore
4.10
自引率
20.00%
发文量
1351
审稿时长
19.04 days
期刊介绍: Minerals (ISSN 2075-163X) is an international open access journal that covers the broad field of mineralogy, economic mineral resources, mineral exploration, innovative mining techniques and advances in mineral processing. It publishes reviews, regular research papers and short notes. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. There is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced.
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