An electro-thermal finite element method (FEM) model for local hotspot kinetics in Cu(In, Ga)Se2 thin-film solar modules

IF 2.7 3区 物理与天体物理 Q2 PHYSICS, APPLIED Journal of Applied Physics Pub Date : 2024-09-17 DOI:10.1063/5.0222051
Suheir Nofal, Timon S. Vaas, Uwe Rau, Bart E. Pieters
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Abstract

Partial shading can significantly impair the efficiency of thin-film solar cells. When exposed to partial shading, cells within the array tend to become reverse biased, leading to thermal runaway events and the emergence of hotspots. In Cu(In,Ga)Se2 (CIGS) solar cells such hotspots are also associated with so-called worm-like defects. Both theoretical and experimental studies have shown that in CIGS, a positive-feedback loop leads to instability and thermal runaway events. However, we observe an inconsistency between published simulation results and recently published experimental work. In a recent experimental study, it was shown that under certain conditions, a hotspot develops within 1ms, showing signs of melting of the CIGS in an area with a 5μm radius. However, in published simulation results, the time for such high temperatures to develop is in the order of seconds, a discrepancy of three orders of magnitude. In this work, we argue that this discrepancy is explained by the size of the seed defect, demonstrating that the origin of these experimentally observed, fast-developing hotspots is likely microscopic defects. To this end, we developed an electro-thermal finite element model, with very high temporal and spatial resolution. We demonstrate that, assuming a seed defect with a 10nm radius, we can reproduce the experimental results with respect to the size of the defect and the time it took to develop.
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铜铟镓硒薄膜太阳能模块局部热点动力学的电热有限元法 (FEM) 模型
局部遮光会严重影响薄膜太阳能电池的效率。在部分遮光的情况下,阵列中的电池容易出现反向偏置,导致热失控事件和热点的出现。在铜铟镓硒(CIGS)太阳能电池中,这种热点也与所谓的蠕虫状缺陷有关。理论和实验研究都表明,在 CIGS 中,正反馈回路会导致不稳定和热失控事件。然而,我们注意到已公布的模拟结果与最近公布的实验结果不一致。最近的一项实验研究表明,在特定条件下,1 毫秒内会出现一个热点,在半径为 5 微米的区域内显示出 CIGS 的熔化迹象。然而,在已公布的模拟结果中,出现这种高温的时间约为几秒,相差三个数量级。在这项工作中,我们认为这种差异可以用种子缺陷的大小来解释,证明这些实验观测到的快速发展热点的起源很可能是微观缺陷。为此,我们开发了一个具有极高时空分辨率的电热有限元模型。我们证明,假设种子缺陷的半径为 10 纳米,我们就能在缺陷大小和形成时间方面重现实验结果。
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来源期刊
Journal of Applied Physics
Journal of Applied Physics 物理-物理:应用
CiteScore
5.40
自引率
9.40%
发文量
1534
审稿时长
2.3 months
期刊介绍: The Journal of Applied Physics (JAP) is an influential international journal publishing significant new experimental and theoretical results of applied physics research. Topics covered in JAP are diverse and reflect the most current applied physics research, including: Dielectrics, ferroelectrics, and multiferroics- Electrical discharges, plasmas, and plasma-surface interactions- Emerging, interdisciplinary, and other fields of applied physics- Magnetism, spintronics, and superconductivity- Organic-Inorganic systems, including organic electronics- Photonics, plasmonics, photovoltaics, lasers, optical materials, and phenomena- Physics of devices and sensors- Physics of materials, including electrical, thermal, mechanical and other properties- Physics of matter under extreme conditions- Physics of nanoscale and low-dimensional systems, including atomic and quantum phenomena- Physics of semiconductors- Soft matter, fluids, and biophysics- Thin films, interfaces, and surfaces
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