Raman Spectroscopic Data of the Quenching Phases of a Pt Solution in a Low Water Reduced Carbonic Fluid at P = 200 and T = 950–1000°C

IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Petrology Pub Date : 2024-09-17 DOI:10.1134/S0869591124700188
A. G. Simakin, O. Yu. Shaposhnikova, S. I. Isaenko, V. N. Devyatova, O. A. Tyutyunnik
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Abstract

Raman spectroscopic data of quenching phases in experiments on the dissolution of Pt in reduced carbonic fluid, containing about 30 mol % of CO, both with and without chlorine at P = 200 MPa and T = 950–1000°C are presented. Water content in the fluid was no more than 4.5 mol %. The only soluble form of Pt determined in the acetone solution of the quenching phases and in the experimental products is platinum carbonyl. Low concentrations of carbonyl (no more than a few ppm) become detectable using Raman spectroscopy due to the SERS effect (Surface-Enhanced Raman Scattering), which is possible in the presence of Pt nanoparticles in the objects under study. Platinum nanoparticles, formed at the decomposition of carbonyls, generates specific photoluminescence (PL) peak approximated by Gaussian with parameters FWHM = 1050–1300 cm–1, kmax = 2050–2100 cm–1 both in acetone solution and experimental samples. The spectra of CO (main band k ≈ 2050 cm–1) adsorbed on Pt nanoparticles supported on glassy carbon, formed during the decomposition of excess CO relative to the CCO buffer, corresponded to nanoparticle sizes of about 2 nm. No convincing evidence of a mixed chloride-carbonyl composition of platinum was found in the spectra, which may reflect the lower thermodynamic stability of these mixed complexes at high P-T parameters. Large concentrations of platinum Pt on carbon (up to 2000–3000 ppm) can be explained by the formation of the Pt-C matrix bond and the weakening of the Pt-CO bond in carbonyls, causing their decomposition. Unusual PL peaks were detected in samples from experiments with chlorine-containing fluids, very reminiscent of the PL background of noble metal nanoparticles and attributed to the effect of carbon nanoparticles.

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P = 200 和 T = 950-1000°C 时铂溶液在低水还原碳流体中的淬火相的拉曼光谱数据
摘要 介绍了在 P = 200 MPa 和 T = 950-1000°C 条件下,铂在含有约 30 摩尔 % CO 的还原碳酸流体中溶解实验中的淬火相的拉曼光谱数据。流体中的水含量不超过 4.5 摩尔%。在淬火相的丙酮溶液和实验产品中,唯一可溶性的铂是羰基铂。由于表面增强拉曼散射(SERS)效应,低浓度的羰基(不超过百万分之几)可以通过拉曼光谱检测到,这在研究对象中存在铂纳米颗粒的情况下是可能的。在丙酮溶液和实验样品中,铂纳米粒子在分解羰基时会产生近似于高斯的特定光致发光(PL)峰,其参数为 FWHM = 1050-1300 cm-1,kmax = 2050-2100 cm-1。吸附在玻璃碳上的铂纳米粒子上的 CO(主带 k ≈ 2050 cm-1)的光谱,是在相对于 CCO 缓冲液的过量 CO 分解过程中形成的,与约 2 nm 大小的纳米粒子相对应。在光谱中没有发现令人信服的铂氯羰基混合成分的证据,这可能反映了这些混合复合物在高 P-T 参数下较低的热力学稳定性。碳上铂铂的高浓度(高达 2000-3000 ppm)可解释为铂-碳基键的形成和铂-羰基键的减弱,从而导致其分解。在含氯流体的实验样品中检测到了不寻常的聚光峰,这与贵金属纳米颗粒的聚光背景非常相似,可归因于碳纳米颗粒的影响。
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来源期刊
Petrology
Petrology 地学-地球科学综合
CiteScore
2.40
自引率
20.00%
发文量
27
审稿时长
>12 weeks
期刊介绍: Petrology is a journal of magmatic, metamorphic, and experimental petrology, mineralogy, and geochemistry. The journal offers comprehensive information on all multidisciplinary aspects of theoretical, experimental, and applied petrology. By giving special consideration to studies on the petrography of different regions of the former Soviet Union, Petrology provides readers with a unique opportunity to refine their understanding of the geology of the vast territory of the Eurasian continent. The journal welcomes manuscripts from all countries in the English or Russian language.
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