Spectroscopic and Thermal Study of the Cyanide-Bridged Heteronuclear Compounds [Cd(NH3)(μ-3-Aminomethylpyridine)M(μ-CN)4]N [M: Pd(II) or Pt(II)]

IF 0.8 4区 化学 Q4 SPECTROSCOPY Journal of Applied Spectroscopy Pub Date : 2024-09-14 DOI:10.1007/s10812-024-01791-z
Dursun Karaağaç, Güneş Süheyla Kürkçüoğlu
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Abstract

New cyanide-bridged heteronuclear compounds, [Cd(NH3)(μ-ampy)M(μ-CN)4]n [ampy = 3-aminomethylpyridine, M: Pd(II) or Pt(II) (hereafter abbreviated as Cd-M-ampy)] have been prepared in powder form and investigated by utilizing elemental analysis, vibrational (FT-IR and Raman) spectroscopy, and thermal analysis. In our previous work, we synthesized the [Cd(NH3)(μ-ampy)Ni(μ-CN)4]n compound and determined its crystal structure. The results of thermal analysis and vibrational spectroscopic show that the structural characteristics of Cd–Ni-ampy and Cd–M-ampy [M: Pd(II) or Pt(II)] compounds are analogous to each other. In these compounds, while the sphere of the center of the M(II) ion has a square pyramidal geometry, the coordination sphere of the Cd(II) ion is identified to have a distorted octahedral geometry. While one amine, one ampy, and four cyanide ligands coordinate to the Cd(II) ion, a three-dimensional coordination polymer forms by the coordination of these ligands to the Cd(II) and M(II) ions. Thermal degradation of the compounds occurs in two steps: degradation of ampy and amine ligands and release of the cyanide groups.

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氰化物桥接异核化合物 [Cd(NH3)(μ-3-氨基甲基吡啶)M(μ-CN)4]N[M:钯(II)或铂(II)] 的光谱和热学研究
我们制备了粉末状的新型氰基杂核化合物 [Cd(NH3)(μ-ampy)M(μ-CN)4]n[ampy = 3-aminomethylpyridine, M: Pd(II) or Pt(II) (以下简称 Cd-M-ampy)],并利用元素分析、振动(傅立叶变换红外光谱和拉曼光谱)和热分析对其进行了研究。在之前的工作中,我们合成了[Cd(NH3)(μ-ampy)Ni(μ-CN)4]n 化合物,并确定了其晶体结构。热分析和振动光谱结果表明,Cd-Ni-ampy 和 Cd-M-ampy [M: Pd(II) 或 Pt(II)]化合物的结构特征相似。在这些化合物中,M(II) 离子中心的配位球呈正方形金字塔几何结构,而 Cd(II) 离子的配位球则呈扭曲的八面体几何结构。一个胺配位体、一个氨配位体和四个氰配位体与 Cd(II) 离子配位,这些配位体与 Cd(II) 离子和 M(II) 离子配位形成三维配位聚合物。化合物的热降解分为两个步骤:氨和胺配体的降解以及氰基的释放。
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来源期刊
CiteScore
1.30
自引率
14.30%
发文量
145
审稿时长
2.5 months
期刊介绍: Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.
期刊最新文献
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