Flame Retarded Adhesive Tapes and Their Influence on the Fire Behavior of Bonded Parts

IF 2.3 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Fire Technology Pub Date : 2024-09-16 DOI:10.1007/s10694-024-01637-2
Vitus Hupp, Bernhard Schartel, Kerstin Flothmeier, Andreas Hartwig
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Abstract

Pressure-sensitive adhesive tapes are used in automotives, railway vehicles and construction, where flame retardancy is of major importance. This is why industrial applicants often buy, and industrial tape manufacturers often produce, flame-retardant adhesive tapes, advertised for their good flammability characteristics. Yet, how flame-retardant tapes influence the fire behavior of bonded materials is a rather open question. To investigate this issue, three different substrates were bonded, using eight double-sided adhesive tapes containing two different carriers and two different flame retardants. The bonded substrates were compared to their monolithic counterparts in terms of flammability, fire behavior and fire stability. The fire behavior of adhesive tape bonded materials differed significantly from the monolithic substrates. The usage of different adhesive tapes let to different burning behavior of the bonded materials mainly due to different carrier systems. In contrast, the implementation of flame retardant into the adhesive had rather minor or no effect on the burning behavior of the bonded substrates despite their positive effect on the flammability of the free-standing tape. The carrier changed the HRR curve in the cone calorimeter and was able to both, reduce and increase fire hazards. Using the carrier with the better fire performance can lower the fire growth rate by 20%, the peak of heat release rate by 27%, and the maximum average rate of heat emission by 30% in cone calorimeter tests. Overall, the fire behavior of bonded materials is a complex interaction between substrate, adhesive, and carrier, and depends on the fire scenario the materials are exposed to.

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阻燃胶带及其对粘合部件火灾行为的影响
压敏胶带用于汽车、铁路车辆和建筑业,其阻燃性能非常重要。因此,工业申请人经常购买阻燃胶带,工业胶带制造商也经常生产阻燃胶带,宣传其良好的阻燃性能。然而,阻燃胶带如何影响粘合材料的防火性能还是一个相当开放的问题。为了研究这个问题,我们使用含有两种不同载体和两种不同阻燃剂的八种双面胶带粘合了三种不同的基材。在可燃性、火灾行为和火灾稳定性方面,将粘合基材与整体基材进行了比较。胶带粘合材料的着火行为与整体基材有很大不同。主要由于载体系统不同,使用不同的胶带会导致粘合材料的燃烧行为不同。相比之下,在粘合剂中加入阻燃剂对粘合基材的燃烧行为影响较小,甚至没有影响,尽管阻燃剂对独立胶带的可燃性有积极影响。载体改变了锥形量热计中的 HRR 曲线,既降低了火灾危险性,又增加了火灾危险性。在锥形量热计测试中,使用防火性能更好的载体可将火灾增长率降低 20%,放热峰值降低 27%,最大平均放热率降低 30%。总之,粘合材料的火灾行为是基材、粘合剂和载体之间复杂的相互作用,并取决于材料所处的火灾环境。
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来源期刊
Fire Technology
Fire Technology 工程技术-材料科学:综合
CiteScore
6.60
自引率
14.70%
发文量
137
审稿时长
7.5 months
期刊介绍: Fire Technology publishes original contributions, both theoretical and empirical, that contribute to the solution of problems in fire safety science and engineering. It is the leading journal in the field, publishing applied research dealing with the full range of actual and potential fire hazards facing humans and the environment. It covers the entire domain of fire safety science and engineering problems relevant in industrial, operational, cultural, and environmental applications, including modeling, testing, detection, suppression, human behavior, wildfires, structures, and risk analysis. The aim of Fire Technology is to push forward the frontiers of knowledge and technology by encouraging interdisciplinary communication of significant technical developments in fire protection and subjects of scientific interest to the fire protection community at large. It is published in conjunction with the National Fire Protection Association (NFPA) and the Society of Fire Protection Engineers (SFPE). The mission of NFPA is to help save lives and reduce loss with information, knowledge, and passion. The mission of SFPE is advancing the science and practice of fire protection engineering internationally.
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