Anisotropic thermal, polarized spectroscopic properties and laser performances of Nd:YVO4 crystal from 20 K to 300 K

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-09-20 DOI:10.1016/j.optlastec.2024.111794
Bing-Tian Lang , Yan-Jie Song , Nan Zong , Zhong-Zheng Chen , Yong Bo , Qin-Jun Peng
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Abstract

Temperature-dependent anisotropic thermal and polarized spectroscopic properties of Nd:YVO4 crystal from liquid hydrogen temperature (20 K) to 300 K have been investigated. Thermal properties, such as thermal conductivity and thermal expansion coefficient (TEC) were presented. The maximum thermal conductivity along a-axis and c-axis are 218.3 W/mK and 238.9 W/mK at ∼ 20 K, respectively, both are over one order of magnitude than that at room temperature. The TEC decreases progressively as temperature drops from room temperature to 20 K. Moreover, the polarized spectroscopic properties including absorption cross section, stimulated emission cross section and fluorescence lifetime have been measured to evaluate laser performance. Furthermore, we experimentally explore continuous wave laser performances under various temperatures. A maximum output power of 1.67 W is obtained at 20 K, corresponding to an optical–optical efficiency of 55.7 %, both are about 3.2 times better than that at room temperature. The near-diffracted-limited operation is also observed at 20 K. Thus, based on the large thermal conductivity, low thermal expansion and high emission cross section, high-power, high-beam-quality and highly efficient Nd:YVO4 lasers can be developed at 20 K.

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20 K 至 300 K Nd:YVO4 晶体的各向异性热、偏振光谱特性和激光性能
研究了 Nd:YVO4 晶体从液氢温度(20 K)到 300 K 的随温度变化的各向异性热和偏振光谱特性。研究显示了热导率和热膨胀系数(TEC)等热特性。在 ∼ 20 K 时,沿 a 轴和 c 轴的最大热导率分别为 218.3 W/mK 和 238.9 W/mK,均比室温下的热导率高出一个数量级。此外,我们还测量了极化光谱特性,包括吸收截面、受激发射截面和荧光寿命,以评估激光性能。此外,我们还通过实验探索了连续波激光器在不同温度下的性能。在 20 K 时可获得 1.67 W 的最大输出功率,相应的光电效率为 55.7%,两者均比室温下高约 3.2 倍。因此,基于大热导率、低热膨胀和高发射截面,在 20 K 温度下可以开发出大功率、高光束质量和高效率的 Nd:YVO4 激光器。
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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