Chain-arranged Ni1-xCox micro/nano particles prepared via a magnetic field-assisted reduction for enhanced electromagnetic wave absorption

Abstract

Transition metal magnetic alloys have garnered extensive interests in electromagnetic wave absorption due to the remarkable magnetic loss capacity and unique magnetism-frequency characteristics. Herein, we report a novel magnetic absorbent of Ni_1-xCo_x micro chains that synthesized through a magnetic field-assisted reduction method. The precipitated Ni_1-xCo_x particles could be connected and aligned during the magnetic reduction process. Due to the modified electronic structure of the Co active site by Ni, the particle size in the Ni_1-xCo_x micro chains noticeably increases with increased x. Meanwhile, the complex dielectric constants exhibit a decreasing trend, which contributes to the improved impedance matching and higher resonance frequencies. The connected Ni_1-xCo_x micro/nano particles not only benefit to the conductive loss, but also strengthened the polarization loss on the contacted interfaces among the particles. As a result, significantly enhanced electromagnetic wave absorption performance was obtained with the minimum reflection loss of −21.0 dB and the effective absorption bandwidth of 3.92 GHz at a thickness of only 1.35 mm. Overall, this work has demonstrated the strategy of designing aligned bimetallic absorbent, possessing great potentials in improving their microwave absorption properties.