Supramolecular chemistry for the incorporation of multi-guest molecules into two-dimensional metal hydroxide hosts

IF 1.7 4区 化学 Bulletin of the Korean Chemical Society Pub Date : 2024-09-02 DOI:10.1002/bkcs.12895
Taeho Kim, Jin Kuen Park, Jae-Min Oh
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Abstract

The incorporation of functional molecules into the interlayer space of layered double hydroxide (LDH) has been extensively studied for its role in immobilization, stabilization, manipulation of the molecular configuration, and the release from the host. To create dramatically enhanced properties and achieve unexpectedly high performances, it is necessary to incorporate multi-guests as well as control the guest-guest interaction. In the present review, we have summarized the multi-guest incorporation into LDH based on the supramolecular chemistry, which provides insights into non-covalent molecular interaction through host-guest chemistry. Four well-known intercalation methods in LDH, that is, coprecipitation, ion exchange, reconstruction, and exfoliation-reassembly, are generally applied to multi-guest intercalation. Combinative methods, in which two different intercalation approaches are combined, are also summarized. The multi-guest incorporation, despite the difficulty involved in its synthesis design, could provide fine-tuned and enhanced properties that are useful for a variety of applications.

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将多客体分子纳入二维金属氢氧化物宿主的超分子化学方法
在层状双氢氧化物(LDH)的层间空间中加入功能分子在固定、稳定、操纵分子构型以及从宿主中释放等方面的作用已得到广泛研究。要想显著增强特性并实现意想不到的高性能,就必须结合多种客体并控制客体与客体之间的相互作用。在本综述中,我们总结了基于超分子化学的 LDH 多宾客掺入方法,从而深入了解了通过主宾客化学实现的非共价分子相互作用。LDH 中四种著名的插层方法,即共沉淀法、离子交换法、重构法和剥离-组装法,一般都适用于多宿主插层。此外,还总结了将两种不同的插层方法结合起来的组合方法。尽管多主插层在合成设计上有一定难度,但它可以提供微调和增强的特性,可用于多种应用。
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来源期刊
Bulletin of the Korean Chemical Society
Bulletin of the Korean Chemical Society Chemistry-General Chemistry
自引率
23.50%
发文量
182
期刊介绍: The Bulletin of the Korean Chemical Society is an official research journal of the Korean Chemical Society. It was founded in 1980 and reaches out to the chemical community worldwide. It is strictly peer-reviewed and welcomes Accounts, Communications, Articles, and Notes written in English. The scope of the journal covers all major areas of chemistry: analytical chemistry, electrochemistry, industrial chemistry, inorganic chemistry, life-science chemistry, macromolecular chemistry, organic synthesis, non-synthetic organic chemistry, physical chemistry, and materials chemistry.
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