One-pot solvothermal synthesis of Bi2S3-CdS sensitized TiO2 NT films for improved photocatalytic performance

IF 3.9 2区 化学 Q2 CHEMISTRY, PHYSICAL Molecular Catalysis Pub Date : 2024-09-24 DOI:10.1016/j.mcat.2024.114560
Junwei Hou , Yingxiao Chen , Mihemanjang Yimiti , Yangfan Xue , Han Zhang , Qingyao Wang
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Abstract

H2 energy causes the increasing attention as the green, environmental friendly energy style, and photocatalytic H2 production is the effective strategy by the inexhaustible solar energy conversion. Herein, CdS-Bi2S3 nanoparticles were decorated on TiO2 nanotube arrays (TiO2 NTs) via one-pot solvothermal synthesis method. The cosensitization effectively extended the optical response region, reduced electron/hole recombination and strengthened the photocatalytic H2 evolution performance. The high photocatalytic H2 evolution rate (79.92 μmol·cm−2·h−1) was obtained by TiO2 NTs/Bi2S3CdS, and the photocatalyst also exhibited dramatically high stability. The photocatalytic water splitting for H2 evolution mechanism and charge carrier transportation were proposed.

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一锅溶热合成 Bi2S3-CdS 敏化 TiO2 NT 薄膜以提高光催化性能
H2 能源作为绿色、环保的能源方式日益受到人们的关注,而光催化制取 H2 是利用取之不尽、用之不竭的太阳能进行转换的有效策略。本文通过一锅溶热合成法在 TiO2 纳米管阵列(TiO2 NTs)上装饰了 CdS-Bi2S3 纳米粒子。共敏化作用有效地扩展了光响应区域,减少了电子/空穴重组,增强了光催化H2进化性能。TiO2 NTs/Bi2S3CdS 获得了很高的光催化 H2 进化率(79.92 μmol-cm-2-h-1),而且该光催化剂还表现出显著的高稳定性。提出了光催化水分离的 H2 演化机理和电荷载流子传输。
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来源期刊
Molecular Catalysis
Molecular Catalysis Chemical Engineering-Process Chemistry and Technology
CiteScore
6.90
自引率
10.90%
发文量
700
审稿时长
40 days
期刊介绍: Molecular Catalysis publishes full papers that are original, rigorous, and scholarly contributions examining the molecular and atomic aspects of catalytic activation and reaction mechanisms. The fields covered are: Heterogeneous catalysis including immobilized molecular catalysts Homogeneous catalysis including organocatalysis, organometallic catalysis and biocatalysis Photo- and electrochemistry Theoretical aspects of catalysis analyzed by computational methods
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