Fatima Setifi , Zouaoui Setifi , David K. Geiger , Mohammed Hadi Al-Douh , Abderezak Addala
{"title":"catena-Poly[[(8-aminoquinoline)cobalt(II)]-di-μ-azido]","authors":"Fatima Setifi , Zouaoui Setifi , David K. Geiger , Mohammed Hadi Al-Douh , Abderezak Addala","doi":"10.1107/S2414314624008496","DOIUrl":null,"url":null,"abstract":"<div><div>[Co(C<sub>9</sub>H<sub>8</sub>N<sub>2</sub>)(N<sub>3</sub>)<sub>2</sub>]<sub>n</sub> exhibits a distorted octahedral coordination geometry. Bridging azide ligands result in chains along [100].</div></div><div><div>The title coordination polymer, [Co(N<sub>3</sub>)<sub>2</sub>(C<sub>9</sub>H<sub>8</sub>N<sub>2</sub>)]<sub>n</sub>, was synthesized solvothermally. The Co<sup>II</sup> atom exhibits a distorted octahedral [CoN<sub>6</sub>] coordination geometry with a bidentate 8-aminoquinoline ligand and four azide ligands. Bridging azide ligands result in chains extending along [100]. N—H⋯N hydrogen bonds join the chains to give an extended structure with sheets parallel to (002).<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (267KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 9","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451032/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S241431462400083X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
[Co(C9H8N2)(N3)2]n exhibits a distorted octahedral coordination geometry. Bridging azide ligands result in chains along [100].
The title coordination polymer, [Co(N3)2(C9H8N2)]n, was synthesized solvothermally. The CoII atom exhibits a distorted octahedral [CoN6] coordination geometry with a bidentate 8-aminoquinoline ligand and four azide ligands. Bridging azide ligands result in chains extending along [100]. N—H⋯N hydrogen bonds join the chains to give an extended structure with sheets parallel to (002).
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