Silas Martin , William W. Brennessel , Ammar Hasan , Carly R. Reed
{"title":"Bis[2-(isoquinolin-1-yl)phenyl-κ2N,C1](2-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline-κ2N,N′)iridium(III) hexafluoridophosphate methanol monosolvate","authors":"Silas Martin , William W. Brennessel , Ammar Hasan , Carly R. Reed","doi":"10.1107/S2414314624008599","DOIUrl":null,"url":null,"abstract":"<div><div>The title iridium complex is the first X-ray characterized compound including both 1-phenylisoquinoline and 2-phenyl-1<em>H</em>-imidazo[4,5-<em>f</em>][1,10]phenanthroline ligands.</div></div><div><div>The title compound, [Ir(C<sub>15</sub>H<sub>10</sub>N)<sub>2</sub>(C<sub>19</sub>H<sub>12</sub>N<sub>4</sub>)]PF<sub>6</sub>·CH<sub>3</sub>OH, crystallizes in the <em>C</em>2/<em>c</em> space group with one monocationic iridium complex, one hexafluoridophosphate anion, and one methanol solvent molecule of crystallization in the asymmetric unit, all in general positions. The anion and solvent are linked to the iridium complex cation <em>via</em> hydrogen bonding. All bond lengths and angles fall into expected ranges compared to similar compounds.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (253KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451029/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000877","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
The title iridium complex is the first X-ray characterized compound including both 1-phenylisoquinoline and 2-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline ligands.
The title compound, [Ir(C15H10N)2(C19H12N4)]PF6·CH3OH, crystallizes in the C2/c space group with one monocationic iridium complex, one hexafluoridophosphate anion, and one methanol solvent molecule of crystallization in the asymmetric unit, all in general positions. The anion and solvent are linked to the iridium complex cation via hydrogen bonding. All bond lengths and angles fall into expected ranges compared to similar compounds.
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