Ti4Fe2C0.82O0.18

IUCrData Pub Date : 2024-09-01 DOI:10.1107/S2414314624008903

Huizi Liu , Changzeng Fan , Bin Wen , Lifeng Zhang

{"title":"Ti4Fe2C0.82O0.18","authors":"Huizi Liu , Changzeng Fan , Bin Wen , Lifeng Zhang","doi":"10.1107/S2414314624008903","DOIUrl":null,"url":null,"abstract":"<div><div>Ti4Fe2C0.82O0.18 is the first example where C and O atoms co-occupy the same site in filled Ti2Fe structures.</div></div><div><div>The phase with composition Ti4Fe2C0.82O0.18, tetratitanium diiron carbide oxide, was unexpectedly synthesized by high-pressure sintering (HPS) of a stoichiometric mixture with nominal composition Ti2Fe. The Ti4Fe2C0.82O0.18 phase crystallizes in the Fd<blockquote><div><figure><img></figure></div></blockquote>m space group and can be considered as the Ti2Fe structure filled with C and O atoms co-occupying the same octahedral void [occupancy ratio 0.82 (7):0.18 (7)]. The Ti4Fe2C0.82O0.18 phase is isotypic with Ti4Ni2C and Ti4Fe2O0.407, and is the first example where C and O atoms co-occupy the same site in filled Ti2Fe structures.<figure><img><ol><li>Download: Download high-res image (272KB)</li><li>Download: Download full-size image</li></ol></figure></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451028/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000853","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

Abstract

Ti₄Fe₂C_0.82O_0.18 is the first example where C and O atoms co-occupy the same site in filled Ti₂Fe structures.

The phase with composition Ti₄Fe₂C_0.82O_0.18, tetratitanium diiron carbide oxide, was unexpectedly synthesized by high-pressure sintering (HPS) of a stoichiometric mixture with nominal composition Ti₂Fe. The Ti₄Fe₂C_0.82O_0.18 phase crystallizes in the Fd

m space group and can be considered as the Ti₂Fe structure filled with C and O atoms co-occupying the same octahedral void [occupancy ratio 0.82 (7):0.18 (7)]. The Ti₄Fe₂C_0.82O_0.18 phase is isotypic with Ti₄Ni₂C and Ti₄Fe₂O_0.407, and is the first example where C and O atoms co-occupy the same site in filled Ti₂Fe structures.

Download: Download high-res image (272KB)
Download: Download full-size image

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Ti4Fe2C0.8O0.18。

通过高压烧结（HPS）标称成分为 Ti2Fe 的化学计量混合物，意外合成了成分为 Ti4Fe2C0.82O0.18 的四钛二铁碳化物相。Ti4Fe2C0.82O0.18 相在 Fd m 空间群中结晶，可视为填充了 C 原子和 O 原子的 Ti2Fe 结构，它们共同占据同一个八面体空隙[占据比为 0.82 (7):0.18 (7)]。Ti4Fe2C0.82O0.18 相与 Ti4Ni2C 和 Ti4Fe2O0.407 同型，是填充 Ti2Fe 结构中 C 原子和 O 原子共占同一位点的第一个实例。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文去求助

来源期刊

IUCrData

CiteScore

0.30

自引率

0.00%

发文量