Correction to “Regioselective Hydroboration of Unsymmetrical Internal Alkynes Catalyzed by a Cobalt Pincer-NHC Complex”

Abstract

We were made aware of an additional early discovery reported by Petit and co-workers on the cis-α-addition strategy for aryl-alkyl alkynes, which employed a phosphine-based ligand-substituted Cobalt-hydride catalyst. Thus, reference 10 in the original paper should be read as follows. (10) (a) Ferrand, L.; Lyu, Y.; Rivera-Hernández, A.; Fallon, B. J.; Amatore, M.; Aubert, C.; Petit, M. Hydroboration and Diboration of Internal Alkynes Catalyzed by a Well-Defined Low-Valent Cobalt Catalyst. Synthesis 2017, 49, 3895–3904.10.1055/s-0036-1588996. (b) Obligacion, J. V.; Neely, J. M.; Yazdani, A. N.; Pappas, I.; Chirik, P. J. Cobalt Catalyzed Z-Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity. J. Am. Chem. Soc., 2015, 137, 5855–5858.10.1021/jacs.5b00936 (c) Ben-Daat, H.; Rock, C. L.; Flores, M.; Groy, T. L.; Bowman, A. C.; Trovitch, R. J. Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst. Chem. Commun. 2017, 53, 7333–7336.10.1039/C7CC02281F (d) Zhang, G.; Wu, S.; Li, J.; Zeng, H.; Mo, Z.; Davis, K.; Zheng, S. Highly efficient and selective hydroboration of terminal and internal alkynes catalysed by a cobalt(II) coordination polymer. Org. Chem. Front. 2019, 6, 3228–3233.10.1039/C9QO00834A (e) González, M. J.; Bauer, F.; Breit, B. Cobalt-Catalyzed Hydroboration of Terminal and Internal Alkynes. Org. Lett. 2021, 23, 8199–8203.10.1021/acs.orglett.1c02854 (f) Blasius, C. K.; Vasilenko, V.; Matveeva, R.; Wadepohl, H.; Gade, L. H. Reaction Pathways and Redox States in α-Selective Cobalt-Catalyzed Hydroborations of Alkynes. Angew. Chem., Int. Ed. 2020, 59, 23010–23014.10.1002/anie.202009625 (g) Bories, C. C.; Sodreau, A.; Barbazanges, M.; Petit, M. Well-Defined Low-Valent Cobalt Complexes in Catalysis: An Overview. Organometallics, 2024, 43, 895–923.10.1021/acs.organomet.4c00054 This article has not yet been cited by other publications.